•  
  •  
 

Corresponding Author

Ya-wen TANG

Abstract

The electrocatalytic performance of the Ir/C catalyst as the anodic catalyst in the amperometric and electrochemical NH3 sensor was investigated.The experimental results illustrated that in the NaClO4 neutral electrolyte,the electrocatalytic performance of the Ir/C catalyst for the NH3 oxidation is related to the Ir loading in the Ir/C catalyst.Among the Ir/C catalysts with different Ir loading,the best electrocatalytic activity,stability and sensitivity were achieved by the Ir/C catalyst with 10% Ir loadings.In addition,the current densities of the NH3 oxidation at the Ir/C catalysts with the different Ir loadings were linearly proportional to the NH3 concentration.The Ir/C catalyst has a potential application in the amperometric and electrochemical NH3 sensor.

Keywords

Ir/C catalyst, ammonia oxidation, Ir loading, activity

Publication Date

2009-11-28

Online Available Date

2009-11-28

Revised Date

2009-11-28

Received Date

2009-11-28

References

[1]Timmer B,Olthuis W,van den Berg A.Ammonia sen-sors and their applications-a review[J].Sensors andActuators B:Chemical,2005,107:666-677.
[2]Papapolymerou G,Bontozoglou V.Decomposition ofNH3on Pd and Ir comparison with Pt and Rh[J].J MolCatal A,1997,120:165-171.
[3]de Mishima B A L,Lescano D,Holgado T M.et al.Electrochemical oxidation of ammonia in alkaline solu-tions:its application to an amperometric sensor[J].Electrochim Acta,1998,43:395-404.
[4]de Vooys A C A,Koper M T M,van Santen R A,etal.The role of adsorbents in the electrochemical oxida-tion of ammonia on noble and transition metal electrodes[J].J Electroanal Chem,2001,506:127-137.
[5]de Vooys A C A,Mrozek M F,Koper M T M,et al.The nature of chemisorbates formed from ammonia ongold and palladium electrodes as discerned from surface-enhanced Raman spectroscopy[J].Electrochem Com-mun,2001,3:293-298.
[6]Yao K,Cheng Y F.Electrodeposited Ni-Pt binary alloysas electrocatalysts for oxidation of ammonia[J].J PowerSources,2007,173:96-101.
[7]Endo K,Nakamura K,Katayama Y,et al.Pt-Me(Me=Ir,Ru,Ni)binary alloys as an ammonia oxidationanode[J].Electrochim Acta,2004,49:2503-2509.
[8]Endo K,Katayama Y,Miura T.Pt-Ir and Pt-Cu binaryalloys as the electrocatalyst for ammonia oxidation[J].Electrochim Acta,2004,49:1635-1638.
[9]Gootzen J F E,Wonders A H,Visscher W,et al.DEMS and cyclic voltammetry study of NH3oxidation onplatinized platinum[J].Electrochim Acta,1998,43:1851-1856.
[10]Vidal-Iglesias F J,Solla-Gulln J,Rodrguez P,et al.Shape-dependent electrocatalysis:ammonia oxidationon platinum nanoparticles with preferential(100)sur-faces[J].Electrochem Commun,2004,6:1080-1084.
[11]Vidal-Iglesias F J,Solla-Gulln J,Prez J M,et al.Evidence by SERS of azide anion participation in am-monia electrooxidation in alkaline medium on nano-structured Pt electrodes[J].Electrochem Commun,2006,8:102-106.
[12]Vidal-Iglesias F J,Solla-Gulln J,Montiel V,et al.Screening of electrocatalysts for direct ammonia fuelcell:Ammonia oxidation on PtMe(Me:Ir,Rh,Pd,Ru)and preferentially oriented Pt(100)nanoparticles[J].J Power Sources,2007,171:448-456.
[13]Xu J B,Hua K F,Wang Y J,et al.Study on ampero-metric NH3sensor[J].J Zhengzhou College of LightIndustry(Natural Science),2004,19:39-42.
[14]Han Y P,Luo P,Lu TH,et al.Electrochemical oxi-dation of ammonia on Ir anode in potential fixed elec-trochemical sensor[J].Chem Res Chinese Universi-ties,2008,24:1-4.
[15]Radmilovic V,Gasteiger H A,Ross P N.Structureand chemical composition of a supported Pt-Ru electro-catalyst for methanol oxidation[J].J Catalysis,1995,154:98-106.
[16]Antolini E,Cardellini F.Formation of carbon suppor-ted PtRu alloys;an XRD analysis[J].J Alloys Com-pounds,2001,315:118-122.

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.