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Corresponding Author

Xian-zhu FU(xz.fu@siat.ac.cn);
Rong SUN(rong.sun@siat.ac.cn)

Abstract

Graphene is a kind of ideal two-dimensional flat carbon nanomaterials which have unique chemical and physical properties. The attractive potential applications must be based on the high quality mass production of graphene. However, it remains a huge challenge.An electrochemical approach is a fast, environmental friendly and easy-operating method. single- or multi-layered graphene flakes can easily be produced in short periods of time. In this review, the structure, properties and preparation methods of graphene are first introduced. Accordingly, the electrochemical approaches used for the productions of graphene flakes,graphene/inorganic nanocomposites, graphene/polymer composites and graphene analogues are highlighted. Finally, challenges and opportunities are briefly outlined on the graphene flakes and their composites synthesized by electrochemical methods.

Graphical Abstract

Keywords

graphene, graphene composites, electrochemically exfoliation, electrochemically oxidation, electrochemically reduction

Publication Date

2016-02-29

Online Available Date

2016-02-29

Revised Date

2015-12-07

Received Date

2015-11-07

References

[1] Novoselov K S, Geim A K, Morozov S V, et al. Electric field effect in atomically thin carbon films[J]. Science, 2004, 306(5696): 666-669.

[2] Georgakilas V, Perman J A, Tucek J, et al. broad family of carbon nanoallotropes: Classification, chemistry, and applications of fullerenes, carbon dots, nanotubes, graphene, nanodiamonds, and combined superstructures[J]. Chemical Reviews, 2015, 115(11): 4744-4822.

[3] Geng D, Wang H, Yu G. Graphene single crystals: Size and morphology engineering[J]. Advanced Materials, 2015, 27(18): 2821-2837.

[4] Burghard M, Klauk H, Kern K. Carbon-based field-effect transistors for nanoelectronics[J]. Advanced Materials, 2009, 21(25/26): 2586-2600.

[5] Roy-Mayhew J D, Aksay I A. Graphene materials and their use in dye-sensitized solar cells[J]. Chemical Reviews, 2014, 114(12): 6323-6348.

[6] Li W W, Geng X M, Guo Y F, et al. Reduced graphene oxide electrically contacted graphene sensor for highly sensitive nitric oxide detection[J]. ACS Nano, 2011, 5(9): 6955-6961.

[7] Xu Y T, Guo Y, Li C, et al. Graphene oxide nano-sheets wrapped Cu2O microspheres as improved performance anode materials for lithium ion batteries[J]. Nano Energy, 2015, 11: 38-47.

[8] Xu Y T, Guo Y, Song L X, et al. Co-reduction self-assembly of reduced graphene oxide nanosheets coated Cu2O sub-microspheres core-shell composites as lithium ion battery anode materials[J]. Electrochimica Acta, 2015, 176: 434-441.

[9] Ma Y, Chang H, Zhang M, et al. Graphene-based materials for lithium-ion hybrid supercapacitors[J]. Advanced Materials, 2015, 27(36): 5296-5308.

[10] Zhao B, Huang S Y, Wang T, et al. Hollow SnO2@Co3O4 core-shell spheres encapsulated in three-dimensional graphene foams for high performance supercapacitors and lithium-ion batteries[J]. Journal of Power Sources, 2015, 298: 83-91.

[11] Huang S Y, Zhao B, Zhang K, et al. Enhanced reduction of graphene oxide on recyclable Cu foils to fabricate graphene films with superior thermal conductivity[J]. Scientific Reports, 2015, 5: 14260.

[12] Li C, Xu Y T, Zhao B, et al. Flexible graphene electrothermal films made from electrochemically exfoliated graphite[J]. Journal of Materials Science, 2016, 51(2): 1043-1051.

[13] Janas D, Koziol K K. A review of production methods of carbon nanotube and graphene thin films for electrothermal applications[J]. Nanoscale, 2014, 6(6): 3037-3045.

[14] Ye D, Moussa S, Ferguson J D, et al. Highly efficient electron field emission from graphene oxide sheets supported by nickel nanotip arrays[J]. Nano letters, 2012, 12(3): 1265-1268.

[15] Xiong B, Zhou Y, Zhao Y, et al. The use of nitrogen-doped graphene supporting Pt nanoparticles as a catalyst for methanol electrocatalytic oxidation[J]. Carbon, 2013, 52: 181-192.

[16] Van Noorden R. Moving towards a graphene world[J]. Nature, 2006, 442(7100): 228-229.

[17] Hernandez Y, Nicolosi V, Lotya M, et al. High-yield production of graphene by liquid-phase exfoliation of graphite[J]. Nature Nanotechnology, 2008, 3(9): 563-568.

[18] Choucair M, Thordarson P, Stride J A. Gram-scale production of graphene based on solvothermal synthesis and sonication[J]. Nature Nanotechnology, 2009, 4(1): 30-33.

[19] Kim K S, Zhao Y, Jang H, et al. Large-scale pattern growth of graphene films for stretchable transparent electrodes[J]. Nature, 2009, 457(7230): 706-710.

[20] Wei D, Grande L, Chundi V, et al. Graphene from electrochemical exfoliation and its direct applications in enhanced energy storage devices[J]. Chemical Communications, 2012, 48(9): 1239-1241.

[21] Abdelkader A M, Cooper A J, Dryfe R A W, et al. How to get between the sheets: A review of recent works on the electrochemical exfoliation of graphene materials from bulk graphite[J]. Nanoscale, 2015, 7(16): 6944-6956.

[22] Parvez K, Wu Z S, Li R, et al. Exfoliation of graphite into graphene in aqueous solutions of inorganic salts[J]. Journal of the American Chemical Society, 2014, 136(16): 6083-6091.

[23] Ambrosi A, Chua C K, Bonanni A, et al. Electrochemistry of graphene and related materials[J]. Chemical Reviews, 2014, 114(14): 7150-7188.

[24] Pang S, Englert J M, Tsao H N, et al. Extrinsic corrugation-assisted mechanical exfoliation of monolayer graphene[J]. Advanced Materials, 2010, 22(47): 5374-5277.

[25] Yi M, Shen Z. A review on mechanical exfoliation for the scalable production of graphene[J]. Journal of Materials Chemistry A, 2015, 3(22): 11700-11715.

[26] Paton K R, Varrla E, Backes C, et al. Scalable production of large quantities of defect-free few-layer graphene by shear exfoliation in liquids[J]. Nature Materials, 2014, 13(6): 624-630.

[27] Ciesielski A, Haar S, El Gemayel M, et al. Harnessing the liquid-phase exfoliation of graphene using aliphatic compounds: A supramolecular approach[J]. Angewandte Chemie-International Edition, 2014, 53(39): 10355-10361.

[28] Chua CK, Pumera M. Chemical reduction of graphene oxide: A synthetic chemistry viewpoint[J]. Chemical Society Reviews, 2014, 43(1): 291-312.

[29] Thakur S, Karak N. Alternative methods and nature-based reagents for the reduction of graphene oxide: A review[J]. Carbon, 2015, 94: 224-242.

[30] Jiao L, Zhang L, Wang X, et al. Narrow graphene nanoribbons from carbon nanotubes[J]. Nature, 2009, 458(7240): 877-880.

[31] Kosynkin D V, Higginbotham A L, Sinitskii A, et al. Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons[J]. Nature, 2009, 458(7240): 872-U5.

[32] Chen Z P, Ren W C, Gao L B, et al. Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition[J]. Nature Materials, 2011, 10(6): 424-428.

[33] Bointon T H, Barnes M D, Russo S, et al. High quality monolayer graphene synthesized by resistive heating cold wall chemical vapor deposition[J]. Advanced Materials, 2015, 27(28): 4200-4206.

[34] Lewis A M, Derby B, Kinloch I A. Influence of gas phase equilibria on the chemical vapor deposition of graphene[J]. ACS Nano, 2013, 7(4): 3104-3117.

[35] Jiang L, Niu T C, Lu X Q, et al. Low-temperature, bottom-up synthesis of graphene via a radical-coupling reaction[J]. Journal of the American Chemical Society, 2013, 135(24): 9050-9054.

[36] Liu N, Luo F, Wu H X, et al. One-step ionic-liquid-assisted electrochemical synthesis of ionic-liquid-functionalized graphene sheets directly from graphite[J]. Advanced Functional Materials, 2008, 18(10): 1518-1525.

[37] Hathcock K W, Brumfield J C, Goss C A, et al. Incipient electrochemical oxidation of highly oriented pyrolytic graphite: Correlation between surface blistering and electrolyte anion intercalation[J]. Analytical Chemistry, 1995, 67(13): 2201-2206.

[38] Zhang J D, Wang E K. STM investigation of HOPG superperiodic features caused by electrochemical pretreatment[J]. Journal of Electroanalytical Chemistry, 1995, 399(1/2): 83-89.

[39] Choo H S, Kinumoto T, Jeong S K, et al. Mechanism for electrochemical oxidation of highly oriented pyrolytic graphite in sulfuric acid solution[J]. Journal of The Electrochemical Society, 2007, 154(10): B1017-B1023.

[40] Kakaei K. One-pot electrochemical synthesis of graphene by the exfoliation of graphite powder in sodium dodecyl sulfate and its decoration with platinum nanoparticles for methanol oxidation[J]. Carbon, 2013, 51: 195-201.

[41] Cooper A J, Wilson N R, Kinloch I A, et al. Single stage electrochemical exfoliation method for the production of few-layer graphene via intercalation of tetraalkylammonium cations[J]. Carbon, 2014, 66: 340-350.

[42] Wu L Q, Li W W, Li P, et al. Powder, paper and foam of few-layer graphene prepared in high yield by electrochemical intercalation exfoliation of expanded graphite[J]. Small, 2014, 10(7): 1421-1429.

[43] Morales G M, Schifani P, Ellis G, et al. High-quality few layer graphene produced by electrochemical intercalation and microwave-assisted expansion of graphite[J]. Carbon, 2011, 49(8): 2809-2816.

[44] Winchester A J, Ghosh S, Feng S, et al. Electrochemical characterization of liquid-phase exfoliated 2D layers of molybdenum disulfide[J]. ACS Appllied Materials & Interfaces, 2014, 6(3): 2125-2130.

[45] Bonanni A, Pumera M. Surfactants used for dispersion of graphenes exhibit strong influence on electrochemical impedance spectroscopic response[J]. Electrochemistry Communications, 2012, 16(1): 19-21.

[46] Zhu Y, Murali S, Cai W, et al. Graphene and graphene oxide: Synthesis, properties, and applications[J]. Advanced Materials, 2010, 22(35): 3906-3924.

[47] Ferrari A C, Basko D M. Raman spectroscopy as a versatile tool for studying the properties of graphene[J]. Nature nanotechnology, 2013, 8(4): 235-246.

[48] Zhou M, Tang J, Cheng Q, et al. Few-layer graphene obtained by electrochemical exfoliation of graphite cathode[J]. Chemical Physics Letters, 2013, 572: 61-65.

[49] Abdelkader A M, Kinloch I A, Dryfe RAW. Continuous electrochemical exfoliation of micrometer-sized graphene using synergistic ion intercalations and organic solvents[J]. ACS Appllied Materials & Interfaces. 2014, 6(3): 1632-1639.

[50] Ferrari A, Meyer J, Scardaci V, et al. Raman spectrum of graphene and graphene layers[J]. Physical review letters, 2006, 97(18): 187401.

[51] Huang H, Xia Y, Tao X Y, et al. Highly efficient electrolytic exfoliation of graphite into graphene sheets based on Li ions intercalation-expansion-microexplosion mechanism[J]. Journal of Materials Chemistry, 2012, 22(21): 10452-10456.

[52] Van Thanh D, Li L J, Chu C W, et al. Plasma-assisted electrochemical exfoliation of graphite for rapid production of graphene sheets[J]. RSC Advances, 2014, 4(14): 6946-6949.

[53] Zhou M, Wang Y L, Zhai Y M, et al. Controlled synthesis of large-area and patterned electrochemically reduced graphene oxide films[J]. Chemistry-A European Journal, 2009, 15(25): 6116-6120.

[54] Guo Y L, Wu B, Liu H T, et al. Electrical assembly and reduction of graphene oxide in a single solution step for use in flexible sensors[J]. Advanced Materials, 2011, 23(40): 4626-4630.

[55] Kauppila J, Kunnas P, Damlin P, et al. Electrochemical reduction of graphene oxide films in aqueous and organic solutions[J]. Electrochimica Acta, 2013, 89: 84-89.

[56] Lindfors T, Österholm A, Kauppila J, et al. Electrochemical reduction of graphene oxide in electrically conducting poly(3, 4-ethylenedioxythiophene) composite films[J]. Electrochimica Acta, 2013, 110: 428-436.

[57] Tong H, Zhu J, Chen J, et al. Electrochemical reduction of graphene oxide and its electrochemical capacitive performance[J]. Journal of Solid State Electrochemistry, 2013, 17(11): 2857-2863.

[58] Zhang X, Zhang D C, Chen Y, et al. Electrochemical reduction of graphene oxide films: Preparation, characterization and their electrochemical properties[J]. Chinese Science Bulletin, 2012, 57(23): 3045-3050.

[59] Guo Y, Zhang L, Zhao B, et al. A novel solid-to-solid electrocatalysis of graphene oxide reduction on copper electrode[J]. RSC Advances, 2015, 5(107): 87987-87992.

[60] Liu A R, Li C, Bai H, et al. Electrochemical deposition of polypyrrole/sulfonated graphene composite films[J]. The Journal of Physical Chemistry C, 2010, 114(51): 22783-22789.

[61] Shao Y Y, Wang J, Engelhard M, et al. Facile and controllable electrochemical reduction of graphene oxide and its applications[J]. Journal of Materials Chemistry, 2010, 20(4): 743-748.

[62] Chen L Y, Tang Y H, Wang K, et al. Direct electrodeposition of reduced graphene oxide on glassy carbon electrode and its electrochemical application[J]. Electrochemistry Communications, 2011, 13(2): 133-137.

[63] Liu C B, Wang K, Luo S L, et al. Direct electrodeposition of graphene enabling the one-step synthesis of graphene-metal nanocomposite films[J]. Small, 2011, 7(9): 1203-1206.

[64] Li C, Shi G. Three-dimensional graphene architectures[J]. Nanoscale, 2012, 4(18): 5549-5563.

[65] Chen K W, Chen L B, Chen Y Q, et al. Three-dimensional porous graphene-based composite materials: Electrochemical synthesis and application[J]. Journal of Materials Chemistry, 2012, 22(39): 20968-20976.

[66] Liu C G, Yu Z N, Neff D, et al. Graphene-based supercapacitor with an ultrahigh energy density[J]. Nano letters, 2010, 10(12): 4863-4868.

[67] Hu J, Kang Z, Li F, et al. Graphene with three-dimensional architecture for high performance supercapacitor[J]. Carbon, 2014, 67: 221-229.

[68] Patil U, Sohn J, Kulkarni S, et al. Enhanced supercapacitive performance of chemically grown cobalt-nickel hydroxides on three-dimensional graphene foam electrodes[J]. ACS Appllied Materials & Interfaces, 2014, 6(4): 2450-2458.

[69] Yan T, Li R Y, Li Z J. Nickel-cobalt layered double hydroxide ultrathin nanoflakes decorated on graphene sheets with a 3D nanonetwork structure as supercapacitive materials[J]. Materials Research Bulletin, 2014, 51: 97-104.

[70] Wu C H, Deng S X, Wang H, et al. Preparation of novel three dimensional NiO/ultrathin derived graphene hybrid for supercapacitor applications[J]. ACS Appllied Materials & Interfaces, 2014, 6(2): 1106-1112.

[71] Kosynkin D V, Higginbotham A L, Sinitskii A, et al. Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons[J]. Nature, 2009, 458(7240): 872-876.

[72] Jiao L Y, Zhang L, Wang X R, et al. Narrow graphene nanoribbons from carbon nanotubes[J]. Nature, 2009, 458(7240): 877-880.

[73] Shinde D B, Debgupta J, Kushwaha A, et al. Electrochemical unzipping of multi-walled carbon nanotubes for facile synthesis of high-quality graphene nanoribbons[J]. Journal of the American Chemical Society, 2011, 133(12): 4168-4171.

[74] Xie L M, Wang H L, Jin C H, et al. Graphene nanoribbons from unzipped carbon nanotubes: Atomic structures, Raman spectroscopy, and electrical properties[J]. Journal of the American Chemical Society, 2011, 133(27): 10394-10397.

[75] Huang X, Yin Z Y, Wu S X, et al. Graphene-based materials: Synthesis, characterization, properties, and applications[J]. Small, 2011, 7(14): 1876-1902.

[76] Xiong Z G, Zhang L L, Ma J Z. Photocatalytic degradation of dyes over graphene-gold nanocomposites under visible light irradiation[J]. Chemical Communications, 2010, 46(33): 6099-6101.

[77] Xia B Y, Wang B, Wu H B, et al. Sandwich-structured TiO2-Pt-graphene ternary hybrid electrocatalysts with high efficiency and stability[J]. Journal of Materials Chemistry, 2012, 22(32): 16499-16505.

[78] Zhang Z, Xu F G, Yang W S, et al. A facile one-pot method to high-quality Ag-graphene composite nanosheets for efficient surface-enhanced Raman scattering[J]. Chemical Communications, 2011, 47(22): 6440-6442.

[79] Kim W, Lee T, Han S. Multi-layer graphene/copper composites: Preparation using high-ratio differential speed rolling, microstructure and mechanical properties[J]. Carbon, 2014, 69: 55-65.

[80] Jagannadham K. Thermal conductivity of copper-graphene composite films synthesized by electrochemical deposition with exfoliated graphene platelets[J]. Metallurgical and Materials Transactions B, 2012, 43(2): 316-324.

[81] Liu J, Fu S, Yuan B, et al. Toward a universal “adhesive nanosheet” for the assembly of multiple nanoparticles based on a protein-induced reduction/decoration of graphene oxide[J]. Journal of the American Chemical Society, 2010, 132(21): 7279-7281.

[82] Zhao Y, Zhan L, Tian J, et al. Enhanced electrocatalytic oxidation of methanol on Pd/polypyrrole–graphene in alkaline medium[J]. Electrochimica Acta, 2011, 56(5): 1967-1972.

[83] Elzatahry A A, Abdullah A M, El-Din TAS, et al. Nanocomposite graphene-based material for fuel cell applications[J]. International Journal of Electrochemical Science, 2012, 7(4): 3115-3126.

[84] Marquardt D, Vollmer C, Thomann R, et al. The use of microwave irradiation for the easy synthesis of graphene-supported transition metal nanoparticles in ionic liquids[J]. Carbon, 2011, 49(4): 1326-1332.

[85] Zhang X Y, Li H P, Cui X L, et al. Graphene/TiO2 nanocomposites: Synthesis, characterization and application in hydrogen evolution from water photocatalytic splitting[J]. Journal of Materials Chemistry, 2010, 20(14): 2801-2806.

[86] Liu J C, Bai H W, Wang Y J, et al. Self-assembling TiO2 nanorods on large graphene oxide sheets at a two-phase interface and their anti-recombination in photocatalytic applications[J]. Advanced Functional Materials, 2010, 20(23): 4175-4181.

[87] Yin Z Y, Wu S X, Zhou X Z, et al. Electrochemical deposition of ZnO nanorods on transparent reduced graphene oxide electrodes for hybrid solar cells[J]. Small, 2010, 6(2): 307-312.

[88] Feng X M, Chen N N, Zhang Y, et al. The self-assembly of shape controlled functionalized Graphene/MnO2 composites for supercapacitors[J]. Journal of Materials Chemistry A, 2014, 2(24): 9178-9184.

[89] Yan J, Fan Z J, Wei T, et al. Fast and reversible surface redox reaction of graphene-MnO2 composites as supercapacitor electrodes[J]. Carbon, 2010, 48(13): 3825-3833.

[90] Gao Z Y, Liu J L, Xu F, et al. One-pot synthesis of graphene-cuprous oxide composite with enhanced photocatalytic activity[J]. Solid State Sciences, 2012, 14(2): 276-280.

[91] Wu S X, Yin Z Y, He Q Y, et al. Electrochemical deposition of semiconductor oxides on reduced graphene oxide-based flexible, transparent, and conductive electrodes[J]. The Journal of Physical Chemistry C, 2010, 114(27): 11816-11821.

[92] Zhou G, Wang D W, Li F, et al. Graphene-wrapped Fe3O4 anode material with improved reversible capacity and cyclic stability for lithium ion batteries[J]. Chemistry of Materials, 2010, 22(18): 5306-5313.

[93] Liang Y Y, Li Y G, Wang H L, et al. Co3O4 nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction[J]. Nature Materials, 2011, 10(10): 780-786.

[94] Dong X C, Xu H, Wang X W, et al. 3D graphene-cobalt oxide electrode for high-performance supercapacitor and enzymeless glucose detection[J]. ACS Nano, 2012, 6(4): 3206-3213.

[95] Wang X, Cao X Q, Bourgeois L, et al. N-Doped graphene-SnO2 sandwich paper for high-performance lithium-ion batteries[J]. Advanced Functional Materials, 2012, 22(13): 2682-2690.

[96] Huang Y, Wu D, Wang J, et al. Amphiphilic polymer promoted assembly of macroporous graphene/SnO2 frameworks with tunable porosity for high-performance lithium storage[J]. Small, 2014, 10(11): 2226-2232.

[97] Zhu X J, Hu J, Dai H L, et al. Reduced graphene oxide and nanosheet-based nickel oxide microsphere composite as an anode material for lithium ion battery[J]. Electrochimica Acta, 2012, 64: 23-28.

[98] Xu C, Wang X, Zhu J W. Graphene-metal particle nanocomposites[J]. The Journal of Physical Chemistry C, 2008, 112(50): 19841-19845.

[99] Maiyalagan T, Dong X C, Chen P, et al. Electrodeposited Pt on three-dimensional interconnected graphene as a free-standing electrode for fuel cell application[J]. Journal of Materials Chemistry, 2012, 22(12): 5286-5290.

[100] Fu X W, Liao Z M, Zhou Y B, et al. Graphene/ZnO nanowire/graphene vertical structure based fast-response ultraviolet photodetector[J]. Applied Physics Letters, 2012, 100(22): 223114.

[101] Gao Z W, Jin W F, Zhou Y, et al. Self-powered flexible and transparent photovoltaic detectors based on CdSe nanobelt/graphene Schottky junctions[J]. Nanoscale, 2013, 5(12): 5576-5581.

[102] Kim Y T, Han J H, Hong B H, et al. Electrochemical synthesis of CdSe quantum-dot arrays on a graphene basal plane using mesoporous silica thin-film templates[J]. Advanced Materials, 2010, 22(4): 515-518.

[103] Peng L L, Peng X, Liu B R, et al. Ultrathin two-dimensional MnO2/graphene hybrid nanostructures for high-performance, flexible planar supercapacitors[J]. Nano Letters, 2013, 13(5): 2151-2157.

[104] Sun Y Q, Shi G Q. Graphene/polymer composites for energy applications[J]. Journal of Polymer Science Part B-Polymer Physics, 2013, 51(4): 231-253.

[105] Zhang L, Wu J T, Jiang L. Graphene and its polymer nanocomposites[J]. Progress in Chemistry, 2014, 26(4): 560-571.

[106] Kuilla T, Bhadra S, Yao D H, et al. Recent advances in graphene based polymer composites[J]. Progress in Polymer Science, 2010, 35(11): 1350-1375.

[107] Yan X B, Chen J T, Yang J, et al. Fabrication of free-standing, electrochemically active, and biocompatible graphene oxide-polyaniline and graphene-polyaniline hybrid papers[J]. ACS Appllied Materials & Interfaces, 2010, 2(9): 2521-2529.

[108] Feng X M, Li R M, Ma Y W, et al. One-step electrochemical synthesis of graphene/polyaniline composite film and its applications[J]. Advanced Functional Materials, 2011, 21(15): 2989-2996.

[109] Wang D W, Li F, Zhao J P, et al. Fabrication of graphene/polyaniline composite paper via in situ anodic electropolymerization for high-performance flexible electrode[J]. ACS Nano, 2009, 3(7): 1745-1752.

[110] Tang Y H, Wu N, Luo S L, et al. One-step electrodeposition to layer-by-layer graphene-conducting-polymer hybrid films[J]. Macromolecular Rapid Communications, 2012, 33(20): 1780-1786.

[111] Sangermano M, Chiolerio A, Veronese G P, et al. Graphene-epoxy flexible transparent capacitor obtained by graphene-polymer transfer and UV-induced bonding[J]. Macromolecular Rapid Communications, 2014, 35(3): 355-359.

[112] Huang L, Li C, Shi G Q. High-performance and flexible electrochemical capacitors based on graphene/polymer composite films[J]. Journal of Materials Chemistry A, 2014, 2(4): 968-974.

[113] Xu M S, Liang T, Shi M M, etc. Graphene-like two-dimensional materials[J]. Chemical Reviews, 2013, 113(5): 3766-3798.

[114] Matte HSSR, Gomathi A, Manna A K, et al. MoS2 and WS2 analogues of graphene[J]. Angewandte Chemie-International Edition, 2010, 49(24): 4059-4062.

[115] Joensen P, Frindt R F, Morrison S R. Single-layer MoS2[J]. Materials Research Bulletin, 1986, 21(4): 457-461.

[116] Zeng Z Y, Yin Z Y, Huang X, et al. Single-layer semiconducting nanosheets: High-yield preparation and device fabrication[J]. Angewandte Chemie International Edition, 2011, 50(47): 11093-11097.

[117] Wang H, Sofer Z, Moo JGS, etc. Simultaneous self-exfoliation and autonomous motion of MoS2 particles in water[J]. Chemical Communications, 2015, 51(48): 9899-9902.

[118] Loo A H, Bonanni A, Sofer Z, etc. Exfoliated transition metal dichalcogenides (MoS2, MoSe2, WS2, WSe2): An electrochemical impedance spectroscopic investigation[J]. Electrochemistry Communications, 2015, 50: 39-42.

[119] Liu N, Kim P, Kim J H, etc. Large-area atomically thin MoS2 nanosheets prepared using electrochemical exfoliation[J]. ACS Nano, 2014, 8(7): 6902-6910.

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