Abstract
After treated by HF solution,the surface of Zr(V_(0.2)Mn_(0.2)Ni_(0.54)Mo_(0.06))_(2.4) alloywas transformed from Zr-rich and Mn-rich layer to Ni-rich layer.In this way,the nickel on thesurface could be believed to be the Raney-type nickel, which could obviously shorten the activationcycles,improve electrocatalytic activity and hydrogen adsorption ability.In this paper,the reactionmechanism on the alloy surface(i.e. the mechanism of nickel-catalysis,hydrogen-adsorption andhydrogen-transference)had been investigated.And the impedance spectra were fitted to an equivalentcircuit using a non-linear,least-squares(NLLS)fitting program.
Keywords
Laves phase alloy, Hydrogen-storage electrode, Impedance spectra
Publication Date
1995-08-28
Online Available Date
1995-08-28
Revised Date
1995-08-28
Received Date
1995-08-28
Recommended Citation
Xueping Gao, Huabin Yang, Deying Song, Yunshi Zhang, Zuoxiang Zhou, Wei Zhang, Panwen Shen.
Properties of Zr-based Laves Phase Hydrogen Storage Electrode[J]. Journal of Electrochemistry,
1995
,
1(3): 298-304.
DOI: 10.61558/2993-074X.1298
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol1/iss3/10
References
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