•  
  •  
 

Abstract

A modified electrolytic manganese dioside doped with Bi(Bi-EMD)wasprepared and examined by XRD and XPS.It is predominantly γ-mnO_2 and the Bi exists as Bi_2O_3 inthe modified material.The content of Bi in Bi-EMDs increased with the increasement of Bi ̄(3+)concentration in electrolyte,and reached14.3(wt)% from the bath of 0.008 mol·1 ̄(-1)Bi ̄(3+)+ used.Some Zn /Bi-EMD prototype batteries of AA size were assembled,and which cycle life tests showedthat the Bi-EMD has better reversibility.

Keywords

Electrolytic manganese dioxide, Modified electrode, Rechargeability

Publication Date

1995-11-28

Online Available Date

1995-11-28

Revised Date

1995-11-28

Received Date

1995-11-28

References

1夏熙.可充碱锰电池发展与展望.电池,1994,24(2):782PrabhakarRethinarajJ,etal.Preparationandpropertiesofelectrolyticmanganesedioxide.J.PowerSources,1993,42:3353张胜利等.碱液中的改性二氧化锰的可逆性.电池,1993,23(3):1164DieciuchMA.RechargeablecellswithmodifiedMnO_2cathodes.J.ElectrochemSoc,1988,135:24155WroblowaHS.Rechargeablemanganesedioxideelectredes.J。ElectroanalChem,1987,238:946RobergePR.Rechargeablemanganesedioxideelectrodes.J.PowerSources,1991,34:2337舒东,夏熙.改性电解锰制备及可充性研究.电池,1993,23(2):51

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.