Preparation and Electrochemical Magnesium Insertion Behaviors of MgV_2O_6

Authors

Hua-tang YUAN, Institute of New Energy Material Chemistry, Nankai University.United Academy of Nankai- & Tianjin- University, Tianjin 300071, China;
Li-fang JIAO, Institute of New Energy Material Chemistry, Nankai University.United Academy of Nankai- & Tianjin- University, Tianjin 300071, China;
Jian-sheng CAO, Institute of New Energy Material Chemistry, Nankai University.United Academy of Nankai- & Tianjin- University, Tianjin 300071, China;
Xiu-sheng LIU, Institute of New Energy Material Chemistry, Nankai University.United Academy of Nankai- & Tianjin- University, Tianjin 300071, China;
Ming ZHAO, Institute of New Energy Material Chemistry, Nankai University.United Academy of Nankai- & Tianjin- University, Tianjin 300071, China;
Yong-mei WANG, Institute of New Energy Material Chemistry, Nankai University.United Academy of Nankai- & Tianjin- University, Tianjin 300071, China;

Corresponding Author

Hua-tang YUAN

Abstract

MgV_2O_6was synthesized by conventional solid-state reaction from MgO and V_2O_(5)as starting materials. X-Ray diffraction analysis showed that the prepared sample belongs to the monoclinic structure. Electrochemical magnesium insertion from aprotic electrolytes such as organomagnesium halides into this host was found possible and exhibited charge/discharge circulation.

Keywords

Magnesium ion, Battery, Positive materials, MgV_2O_6

DOI Link

https://doi.org/10.61558/2993-074X.1602

Publication Date

2004-11-28

Online Available Date

2004-11-28

Revised Date

2004-11-28

Received Date

2004-11-28

Recommended Citation

Hua-tang YUAN, Li-fang JIAO, Jian-sheng CAO, Xiu-sheng LIU, Ming ZHAO, Yong-mei WANG. Preparation and Electrochemical Magnesium Insertion Behaviors of MgV_2O_6[J]. Journal of Electrochemistry, 2004 , 10(4): 460-463.
DOI: 10.61558/2993-074X.1602
Available at: https://jelectrochem.xmu.edu.cn/journal/vol10/iss4/15

References

[1]　BurneyHS,TaalbotJB.Reportoftheelectrolyticindustriesfortheyear1990[J].J.Electrochem.Soc.,1991,138(10):3140～3172.
[2]　YUANHua Tang,CAOJian Sheng,ZHOUYong,etal.StudyonelectrochemicalbehaviorofthepositiveelectrodeMg1.2Mn1.8O4inmagnesiumIonbattery[J].ChemicalJournalofChineseUniversities,2002,23(10supplement):16～17.
[3]　GendersJD,PletcherD.SudiesusingmicroelectrodesoftheMg(Ⅱ)/Mgcoupleintetrahydrofuranandpropylenecarbonate[J].J.Electroanal.Chem.,1986,199:93～100.
[4]　MayerA.Electrodepositionofaluminum/magnesiumalloys,andmagnesiumfromorganometallicelectrolytes[J].J.Electrochem.Soc.,1990,137(9):2806～2811.
[5]　Pereira RamosJP,MessinaR,PerichonJ.ElectrochemicalformationofamagnesiumbronzeMgxV2O5insulfone basedelectrolytesat150℃[J].J.Electroanal.Chem.,1987,218:241.
[6]　ShkolverV,HaibachT.CrystalstuctureoftheproductofMg2+insertionintoV2O5singlecrystals[J].J.SolidStateChem.,1996,123:317～323.
[7]　KennethRNewby,AllenBScott.DischargemechanismoftheV2O5electrode[J].J.Electrochem.Soc.,1970,117(2):152～156.
[8]　PetrNovk,WernerScheifele,OttoHaas.Magnesiuminsertionbatteriesanalternativetolithium?[J].J.PowerSources,1995,54:479～482.