Abstract
The new electrolyte salt LiBOB for Li-ion battery was synthesized in laboratory,and series of electrolytes of LiBOB and PC/DEC was compounded.The conductivity of the electrolytes was compared by changing the temperature and concentration.The cycling performance of charging-discharging was also compared by the charging-discharging test,the results showed that the varying regularity of conductivities and cycling stability and capacity were not always identical,but there were a suitable electrolyte for Li/ARG cell.The A.C.impedance and CV were used to test the compatibility of the most suitable electrolyte and ARG anode.Conclusion can be drawn that the ARG anode can be protected very well by SEI film in 0.5 mol·L~(-1)LiBOB-PC/DEC(3∶7).
Keywords
Li-ion battery, Electrolyte, LiBOB, PC, DEC
Publication Date
2006-08-28
Online Available Date
2006-08-28
Revised Date
2006-08-28
Received Date
2006-08-28
Recommended Citation
Ying-kun NING, Bi-tao YU, Fu-shen LI, Wei-hua QIU.
The Property Study of LiBOB-PC/DEC Electrolyte[J]. Journal of Electrochemistry,
2006
,
12(3): 257-261.
DOI: 10.61558/2993-074X.1732
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol12/iss3/4
References
[1]Xu K,Zhang S S,Poese B A,et al.L ith ium b is(oxala-to)borate stab lize graph ite anode in propylene carbonate[J].E lectrochem cal and Solid-state letters,2002,5(11):A259~262.
[2]L ischka U,W ietelm ann U,W egnerM.L ith ium b isox-alatoborate,the production thereof and its use as a con-ducting salt[P].Germ an.Patten:DE 19829030 C1,1999.
[3]Xu K,Zhang S S,Jow T R,et al.L iBOB as salt forlith ium-ion batteries[J].E lectrochem cal and Solid-stateLetters,2002,5(1):A26~A29.
[4]Xu K,Zhang S S,Jow T R.E lectrochem ical impedancestudy of graph ite/electrolyte interface form ed in L iBOB/PC electrolyte[J].Journal of Power Source,2005,143:197~202.
[5]Yu B itao(余碧涛),L i Fushen(李福燊),Q iu W e ihua(仇卫华),et al.The developm ent of lith ium salts forL i-ion battery electrolytes[J].Battery(in Ch inese),2004,34(6):446~448.
[6]Krause L J,Lam anna W,Summ erfield J,et al.Corro-sion of alum inum at h igh voltages in non-aqueous elec-trolytes contain ing perfluoroalkysufonyl in ides;new lith-ium salts for lith ium-ion cells[J].J.Power Sources,1997,68:320.
[7]Ohta A,Koshuna H,Okuno H,et al.Relationsh ip be-tween carbonaceous m aterials and electrolyte in seconda-ry lith ium-ion batteries[J].J.Power Sources,1995,54:6.
[8]Zhuang Quanchao(庄全超),W u Shan(武山),L iuW enshan(刘文山),et al.The research of organ ic elec-trolyte solutions for L i-ion batteries[J].E lectrochem is-try(in Ch inese),2001,7(4):403~412.
[9]Xu W,Angell C A.L iBOB and its derivatives,weaklycoord inating an ions,and the exceptional conductivity ofthe ir nonaqueous solutions[J].E lectrochem ical andSolid-state Letters,2001,4(1):E1~E4.
Included in
Engineering Science and Materials Commons, Materials Chemistry Commons, Materials Science and Engineering Commons, Physical Chemistry Commons, Power and Energy Commons