Abstract
Layered Li[Ni_(0.475)Mn_(0.475)Co_(0.05)]O_(2) materials have been prepared by a solid-state pyrolysis method.Experiments of XRD,SEM,cyclic voltammetry and charge/discharge cycling were carried out.It can be learned that when calclined at 800 ℃,the sample showed the highest first discharge capacity of 178.8 mAh·g~(-1) at a current density of 20 mA/g in the voltage range 2.3~4.6 V.
Keywords
Li battery, Cathode material, Li[Ni_(0.475)Mn_(0.475)Co_(0.05)]O_(2), Solid-state pyrolysis
Publication Date
2006-08-28
Online Available Date
2006-08-28
Revised Date
2006-08-28
Received Date
2006-08-28
Recommended Citation
Li-qin WANG, Li-fang JIAO, Hua-tang YUAN.
Calcined Temperatures Influence on Synthesis and Electrochemistry Charactarization of Li[Ni_(0.475)Mn_(0.475)Co_(0.05)]O_(2) for Li-ion Batteries[J]. Journal of Electrochemistry,
2006
,
12(3): 275-278.
DOI: 10.61558/2993-074X.1736
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol12/iss3/8
References
[1]HAN Jing-li(韩景立),LIU Q ing-guo(刘庆国).In-vestigation of a comp lex lith ium cobalt n ickel oxide aslith ium ion battery cathode m aterials prepared by a newc itrate sol-gel m ethod[J].E lectrochem istry(in Ch i-nese),2000,6(4):469.
[2]Yao Chen,W ang G X.Synthesis and characterization ofL iCoxMnyN i1-x-yO2as a cathode m aterial for secondarylith ium batteries[J].J.Power Sources,2003,119:184.
[3]K im JM,Chung H T.Role of transition m etals in lay-ered L i[N i,Co,Mn]O2under electrochem ical operation[J].E lectroch im ica Acta,2004,49:3573.
[4]Tran N,Croguennec L,Jordy C.Influence of the syn-thesis route on the electrochem ical properties of L iN i0.425Mn0.425Co0.15O2[J].Solid State Ion ics,2005,176:1539.
[5]Cao H,Zhang Yao.Synthesis and electrochem ical char-acteristics of layered L iN i0.6Co0.2Mn0.2O2cathode m ate-rial for lith ium ion batteries[J].Solid State Ion ics,2005,176:1207.
[6]Sh in H S,Park H S.Synthesis of L i[N i0.475Co0.05Mn0.475]O2cathode m aterials via a carbonate process[J].Solid State Ion ics,2005,176:2577.
[7]Cho TH,Park SM.E ffect of synthesis cond ition on thestructural and electrochem ical properties of L i[N i1/3Mn1/3Co1/3]O2prepared by carbonate co-prec ip itationm ethod[J].J.Power Sources,2005,142:306.
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