Abstract
A novel 1D bamboo-shaped silicon nanotubes was synthesized by chemical vapor deposition with Au catalyst and their electrochemical properties were primarily studied.The results showed that these silicon nanotubes were amorphous with the length about tens micrometer and the diameter about one hundred nanometer.Cyclic voltammetry studies showed that Li ions could intercalate into such silicon nanotubes at two location,i.e.,from the conjoint location and the wall of the hole.Meanwhile,the bamboo-shaped structure could help release the expansion of volume,which is usually serious in the lithium batteries.
Keywords
Anode material, Li-ion battery, Bamboo-shaped Si nanotubes
Publication Date
2006-11-28
Online Available Date
2006-11-28
Revised Date
2006-11-28
Received Date
2006-11-28
Recommended Citation
Zeng-tao LIU, Yan-peng FU, Chen LI, Yong YANG.
Preparation and Electrochemical Property of Bam boo-shaped Silicon Nanotubes[J]. Journal of Electrochemistry,
2006
,
12(4): 363-367.
DOI: 10.61558/2993-074X.1753
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol12/iss4/2
References
[1]M egahed S,Scrosati B.L ith ium-ion rechargeab le bat-teries[J].J.Power Sources,1994,5(1~2):79.
[2]Ohzuku T,Iwakosh i Y,Sawai K.Form ation of lith ium-graph ite intercalation compounds in nonaqueous electro-lytes and the ir app lication as a negative electrode for alith ium ion(shuttlecock)cell[J].J.E lectrochem.Soc.,1993,140:2490.
[3]Aurbach D,E in-E li Y,M arkovsky Y B,et al.Thestudy of electrolyte solutions based on ethylene and d i-ethyl carbonates for rechargeab le L i Batteries[J].J.E lectrochem.Soc.,1995,142(9):2882.
[4]Am ezawa K,Yam amoto N,Tom iiY,et al.S ingle-elec-trode peltier heats of L i-S i alloy electrodes in L iC l-KC leutectic m elt[J].J.E lectrochem.Soc.,1998,145(6):1986.
[5]Huggins,Robert A.L ith ium alloy negative electrodesform ed from convertib le oxides[J].Solid State Ion ics,1998,113~115:57.
[6]L iH,Huang X,Chen L,et al.A h igh capac ity nano-S i composite anode m aterial for lith ium rechargeab lebatteries[J].E lectrochem,Solid State Lett.,1999,2(11):547.
[7]L i H,Huang X,Chen L,et al.The crystal structuralevolution of nano-S i anode caused by lith ium insertionand extraction at room temperature[J].Solid State Ion-ics,2000,135(1~4):181.
[8]L i C,L iu Z T,Yang Y.Controllab le synthesis andgrowth model of amorphous silicon nanotubes w ith peri-od ically dom e-shaped interiors[J].Adv.M ater.,2006,18:228.
[9]L i Chen.Synthesis and characterization of one-d im en-sional sem iconductor nanom aterials[D].X iam en:X ia-m en Un iversity,2005.
[10]Xu M eng-q ing(许梦清),ZUO X iao-xi(左晓希),LIW e i-shan(李伟善),et al.E lectrochem ical behaviorof carbonate solvent used in electrolytes for L i-ion bat-teries[J].Ch inese Battery Industry(in Ch inese),2005,10(5):274.
[11]REN N ing(任宁),Y IN Ge-p ing(尹鸽平),ZUOPeng-jian(左朋建),et al.E lectrochem ical perform-ance of S i-Mn composites in L i-ion battery[J].Ch i-nese Journal of Inorgan ic Chem istry(in Ch inese),2005,21:1677.
[12]SUN Yang-zheng,LIAO X iao-zhen,MA Z i-feng.Re-search progress in silicon based anode m aterials for L i-ion batteries[J].Battery B imonthly,2004,3:40.