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Abstract

Tafel polarization curves and electrochemical impedance spectroscopy(EIS) techniques were employed to investigate the corrosion electrochemical behavior of AZ31 and AZ61 magnesium alloys.Scanning electron microscopy(SEM) was used to observe the alloy microstructure and corrosion morphology.The variation of the bulk corrosive medium pH with immersion time was recorded during the exposure of the alloys to simulated sea water.Results show that AZ61 magnesium alloy exhibits much better anti-corrosion ability than AZ31 magnesium alloy.The different corrosion behavior between the two magnesium alloys is correlated with their different content of Al alloying element.The higher content of Al in AZ61 alloy leads to the homogenerous microstructure and the strong surface passivation,which is helpful for improving the alloy corrosion resistance.

Keywords

magnesium alloy, simulated sea water, corrosion, alloying element

Publication Date

2008-02-28

Online Available Date

2008-02-28

Revised Date

2008-02-28

Received Date

2008-02-28

References

[1]Zhang Jin(张津),Zhang Zong-he(章宗和).Magnesi-um alloys and applications[M].Beijing:Chemical In-dustry Press,2004.47-50.
[2]Li Guan-qun(李冠群),Wu Guo-hua(吴国华),FanYu(樊昱),et al.Effect of the main alloying elementson microstructure and corrosion resistance of magnesiumalloys[J].Foundry Technology(in Chinese),2006,27(1):79-83.
[3]Song Guang-ling(宋光铃).Corrosion and protection ofmagnesium alloys[M].Beijing:Chemical IndustryPress,2006.94-208
[4]Cao Chu-nan(曹楚南).Principles of corrosion electro-chemistry(2nd edition)[M].Beijing:Chemical In-dustry Press,2004.185-187.
[5]Dean John A.Lange’s handbook of chemistry(15th e-dition)[M].McGRAW-HILL,INC,1999.
[6]Song G,Atrens A,Dargusch M.Influence of micro-structure on the corrosion of diecast AZ91D[J].Corro-sion Science,1999,41:249-273.
[7]Ambat R,Aung N N,Zhou W.Evaluation of micro-structural effects on corrosion behaviour of AZ91D mag-nesium alloy[J].Corrosion Science,2000,42:1433-1455.
[8]Mathieu S,Rapin C,Steinmetz J,et al.A corrosionstudy of the main constituent phases of AZ91 magnesiumalloys[J].Corrosion Science,2003,45:2741-2755.
[9]Zhang T,Li Y,Wang F.Roles ofβphase in the corro-sion process of AZ91D magnesium alloy[J].CorrosionScience,2006,48:1249-1264.

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