•  
  •  
 

Abstract

The SiNWs electrodes were fabricated by coating and direct growth methods,respectively.The structure,morphology and electrochemical performance of such materials were characterized by XRD,SEM and charge-discharge tests.The results show that the electrodes prepared by direct growth method had higher capacity,better battery life and also displayed and excellent cyclability at higher currents.During the process of lithiation,the initial crystalline Si transformed to amorphous LixSi,and the average diameter of the SiNWs increased.Despite the large volume changed,the SiNWs remained intact and did not break into smaller particles.

Keywords

Silicon, nanowires, anode materials, electroperformance, lithium-ion batteries, coating method, direct growth method

Publication Date

2009-02-28

Online Available Date

2009-02-28

Revised Date

2009-02-28

Received Date

2009-02-28

References

[1]Fauteux D,Koksbang R.Rechargeable lithium batteryanodes:alternatives to metallic lithium[J].Journal ofApplied Electrochemistry,1993,23:1-10.
[2]Li H,Huang X J,Chen L Q,et al.A high capacitynano-Si composite anode material for lithium recharge-able batteries[J].Electrochemical and Solid State Let-ters,1999,2(11):547-549.
[3]Yang J,Wachtler M,Winter M,et al.Sub-microcrystal-line Sn and Sn-SnSb powders as lithium storage materi-als for lithium-ion batteries[J].Electrochemical andSolid State Letters,1999,2(4):161-163.
[4]Wang C S,Appleby A J,Little F E.Electrochemicalstudy on nano-Sn,Li4.4Sn and AlSi0.1powders used assecondary lithium battery anodes[J].Journal of PowerSources,2001,93(1~2):174-185.
[5]Bourderau S,Brousse T,Schleich D M.Amorphous sili-con as a possible anode material for Li-ion batteries[J].Journal of Power Sources,1999,82:233-236.
[6]Xing W B,Wilson A M,Eguchi K,et al.Pyrolyzed pol-ysiloxanes for use as anode materials in lithium-ion bat-teries[J].Journal of the Electrochemical Society,1997,144(7):2410-2416.
[7]Larcher D,Mudalige C,George A E,et al.Si-containingdisordered carbons prepared by pyrolysis of pitch polysi-lane blends:effect of oxygen and sulfur[J].Solid StateIonics,1999,122(1~4):71-83.
[8]Wang G X,Sun L,Bradhurst D H,et al.Nanocrystal-line NiSi alloy as an anode material for lithium-ion bat-teries[J].Journal of Alloys and Compounds,2000,306(1~2):249-252.
[9]Wang G X,Sun L,Bradhurst D H,et al.Innovativenanosize lithium storage alloys with silica as active cen-tre[J].Journal of Power Sources,2000,88(2):278-281.
[10]Ng S B,Lee J Y,Liu Z L.Si-O network encapsulatedgraphite-silicon mixtures as negative electrodes for lith-ium-ion batteries[J].Journal of Power Sources,2001,94(1),63-67.
[11]Zhou G W,Sun H P,Yu D P,et al.Control Li dopingof Si nanowires by electrochemical insertation method[J].Applied Physics Letters,1999,75(16):2447-2449.
[12]Chan C K,Peng HL,Liu G,et al.High-performancelithium battery anodes using silicon nanowires[J].Na-ture Nanotechnology,2008,3(1):31-35.
[13]Laik B,Eude L,Pereira-Ramos,et al.Siliconnanowires as negative electrode for lithium-ion micro-batteries[J].Electrochimica Acta,2008,53(17):5528-5532.
[14]Liu Z T(刘增涛),Fu Y P(傅焰鹏),Li C(李晨),et al.Preparation and electrochemical property of bam-boo-shaped silicon nanotubes[J].Electrochemistry(in Chinese),2006,12(4):363-367.
[15]Graetz J,Ahn C C,Yazami R,et al.Highly reversiblelithium storage in nanostructured silicon[J].Electro-chemical and Solid State Letters,2003,6(9):A194-A197.
[16]Zane D,Antonini A,Pasquali M.A morphologicalstudy of SEI film on graphite electrodes[J].Journal ofPower Sources,2001,(97~98):146-150.
[17]Li J,Dahn J R.An in situ X-ray diffraction study ofthe reaction of Li with crystalline Si[J].Journal of theElectrochemical Society,2007,154(3):A156-A161.
[18]Wang W,Kumta P N.Reversible high capacity nano-composite anodes of Si/C/SWNTs for rechargeable Li-ion batteries[J].Journal of Power Sources,2007,172(2):650-658.
[19]Hatchard T D,Dahn J R.In situ XRD and electro-chemical study of the reaction of lithium with amor-phous silicon[J].Journal of the Electrochemical Soci-ety,2004,151(6):A838-A842.

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.