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Abstract

The protonated titanate nanoparticles were obtained at room temperature and subsequently calcined at different temperatures(300 ℃,400 ℃,500 ℃,600 ℃ and 700 ℃) in air.The obtained products were characterized by XRD,TEM and UV-Vis.It is found that the grain sizes of TiO2 nanoparticles calcined at 300 ℃ were about 20 nm,and increased gradually with the temperature rise.Photoelectric performance was measured with I~V curve and electrochemical impedance spectroscopy(EIS).The TiO2 nanoparticles obtained at 500 ℃ showed the best photoelectrochemical properties with a photovoltaic conversion efficiency of 6.39%,which is much higher than those at other temperatures.In addition,it is also demonstrated that the charge transfer resistance of TiO2 nanoparticles obtained at 500 ℃ was much smaller.

Keywords

DSSCs, TiO2, nanoparticles, photoelectrochemical properties

Publication Date

2009-02-28

Online Available Date

2009-02-28

Revised Date

2009-02-28

Received Date

2009-02-28

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