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Corresponding Author

Li YANG

Abstract

Spinel lithium titanate(Li4Ti5O12) nanosheets with a size range of 200 ~400 nm were synthesized by hydrothermal process from the amorphous hydrous titanium oxide precursors.The as-prepared products were characterized by X-ray powder diffraction(XRD),scanning electron microscopy(SEM) and transmission electron microscopy(TEM).The electrochemical behaviors of Li4Ti5O12 electrode in conventional organic electrolyte and ionic liquid electrolyte were investigated by using cyclic voltammetry,galvanostatic charge-discharge and AC impedance techniques.The experimental results indicate that the as-prepared nanostructured Li4Ti5O12,evaluated as anode material,exhibited good reversibility and cycle performance.It is expected to be a potential anode material for commerical battery applications.

Keywords

Li4Ti5O12, nanosheet, ionic liquid, electrolyte, lithium ion battery

Publication Date

2010-02-28

Online Available Date

2010-02-28

Revised Date

2010-02-28

Received Date

2010-02-28

References

[1]Aldon L,Kubiak P,Womes M,et al.Chemical and elec-trochemical Li-insertionin to the Li4Ti5O12spinel[J].Chem Mater,2004,16:5721.
[2]Pao P,Prosini O,Mancini R,et al.Li4Ti5O12as anode in all-solid-state,plastic lithium-ion batteries for low-power application[J].Solid State Ionics,2001,144:185-192.
[3]Wang C L,Liao Y C,Hsu F C,et al.Preparation and characterization of thin film Li4Ti5O12electrodes by magnetron sputtering[J].J Electrochem Soc,2005,152(4):A653-A657.
[4]Tang Y F,Yang L,Qiu Z,et al.Preparation and electro-chemical lithium storage of flower-like spinel Li4Ti5O12consisting of nanosheets[J].Electrochem Commun,2008,10:1513-1516.
[5]Tang Y F,Yang L,Qiu Z,et al.Template-free synthesis of mesoporous spinel lithium titanate microspheres and their application in high-rate lithium ion batteries[J].J Mater Chem,2009,19:5980-5984.
[6]Tang Y F,Yang L,Fang S H,et al.Li4Ti5O12hollow mi-crospheres assembled by nanosheets as an anode materi-al for high-rate lithium ion batteries[J].Electrochim Acta,2009,54:6244-6249.
[7]Yan F,Yu X M,Zhang X W.Enhanced proton conduc-tion in polymer electrolyte membranes as synthesized by polymerization of protic ionic liquid-based microemul-sions[J].Chem Mater,2009,21:1480-1484.
[8]Martinelli A,Matic A,Jacobsson P.Physical properties of proton conducting membranes based on a protic ionic liquid[J].J Phys Chem B,2007,111:12462-12467.
[9]Welton T.Room-temperature ionic liquids solvents for synthesis and catalysis[J].Chem Rev,1999,99(8):2071-2083.
[10]Fang S H,Yang L,Wei C,et al.Low-viscosity and low-melting point asymmetric trialkylsulfonium based ionic liquids as potential electrolyte for lithium battery[J].Electrochem Commun,2007,9(11):2696-2702.
[11]Fang S H,Yang L,Wei C,et al.Ionic liquids based on guanidinium cations and TFSI anion as potential elec-trolytes[J].Electrochim Acta,2009,54(6):1752-1756.
[12]Galiński M,Lewandowski A,Stepniak I.Ionic liquids as electrolytes[J].Electrochim Acta,2006,51(26):5567-5580.
[13]Fernicola A,Scrosati B,Ohno H.Potentialities of ionic liquids as new electrolyte media in advanced electro-chemical devices[J].Ionics,2006,12(2):95-102.
[14]Yang L,Zhang Z X,Gao X H,et al.Asymmetric sulfo-nium-based moltensalts with TFSI-or PF6-anion as no-vel electrolytes[J].J Power Sources,2006,162(1):614-619.
[15]Eiden-Assmann S,Widoniak J,Maret G.Synthesis and characterization of porous and nonporous monodisperse colloidal TiO2particles[J].Chem Mater,2004,16(1):6.
[16]Ohzuku T,Ueda A,Yamamoto N.Zero-strain insertion material of Li[Li1/3Ti5/3Ti5/3]O4for rechargeable lithi-um cells[J].J Electrochem Soc,1995,142(5):1431.
[17]Zaghib K,Simoneau M,Armand M.Electrochemical study of Li4Ti5O12as negative electrode for Li-ion poly-mer rechargeable batteries[J].J Power Sources,1999,81:300-305.
[18]Sato T,Maruo T,Marukane S,et al.Ionic liquids con-taining carbonate solvents as electrolytes for lithium ion cells[J].J Power Sources,2004,138(1/2):253-261.
[19]Seki S,Kobayashi Y,Miyashiro H,et al.Lithium sec-ondary batteries using modified-inidazolium room-tem-perature ionic liquid[J].J Phys Chem B,2006,110(21):10228-10230.
[20]Sakaebe H,Matsumoto H.N-Methyl-N-propylpiperidin-ium bis(trifluoromethane-sulfonyl)imide(PP13-TF-SI)-novel electrolyte base for Li battery[J].Electro-chem Commun,2003,5(7):594-598.
[21]Sakaebe H,Matsumoto H,Tatsumi K.Discharge-charge properties of Li/LiCoO2cell using room-temperature i-onic liquids(RTILs)based on quaternary ammonium cation-effect of the structure[J].J Power Sources,2005,146(1/2):693-697.
[22]Holzapfel M,Jost C,Schwab A P,et al.Stabilisation of lithiated graphite in an electrolyte based on ionic liq-uids:an electrochemical and scanning electron micros-copy study[J].Carbon,2005,43(7):1488-1498.
[23]Zheng H,Jiang K,Abe T,et al.Electrochemical inter-calation of lithium into a natural graphite anode in qua-ternary ammonium-based ionic liquid electrolytes[J].Carbon,2006,44(2):203-210.

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