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Abstract

The CeO2-modified PbO2 on Ti plate ( Ti/CeO2-F-PbO2) was prepared by electrodeposition. The SEM and XRD analyses indicated that the CeO2 particle could be beuniformly co-deposited in the film of PbO2. The results of electrochemical test showed that the Ti/CeO2-F-PbO2 anode had higher potential ( 1. 83 V. vs. SCE) for oxygen evolution ( OE) than the Ti/F-PbO2 anode ( 1. 78 V,vs. SCE) . The degradation of 4-chlorophenol was carried out to test electrocatalytic performance of this novel electrode,which indicated that Ti/CeO2-F-PbO2 anode had high COD removal rate and instantaneous current efficiencies ( ICE) .

Keywords

PbO2, doped, CeO2, degradation, 4-chlorophenol

Publication Date

2010-05-28

Online Available Date

2010-05-28

Revised Date

2010-05-28

Received Date

2010-05-28

References

[1]Houk L L,Johnson S K,Feng J.Electrochemical inciner-ation of benzoquinone in aqueous media using a quater-nary metal oxide electrode in the absence of a soluble supporting electrolyte[J].J Appl electrochem,1998,28:1167.
[2]Rodgers J D,Jedral W,Bunce N J.Electrochemical oxi-dation of chlorinated phenols[J].Environ Sci Technol,1999,33:1453.
[3]Zhou Ming-hua(周明华),Dai Qi-zhou(戴启洲),Lei Le-cheng(雷乐成),et al.Electrochemical oxidation for the degradation of organic pollutants on a novel PbO2anode[J].Acta Physico-chimica Sinica(物理化学学报),2004,20(8):871.
[4]Comminellis C,Pulgarin C.Anodic oxidation of phenol for wastewater treatment[J].J Appl Electrochem,1991,21:703.
[5]Awad Y M,Abuzaid N S.Electrochemical oxidation of phenol using graphite anodes[J].Sep Sci Technol,1999,34:699.
[6]Li X Y,Cui Y H,Feng Y J,et al.Reaction pathways and mechanisms of the electrochemical degradation of phenol on different electrodes[J].Water Res,2005,39:1972.
[7]Lozano B C,Comninellis C h,Battisti A D.Service life of Ti/SnO2-Sb2O5anodes[J].J Appl Electrochem,1997,27:970.
[8]Qi Hong-lan(漆红兰),Zhang Cheng-xiao(张成孝).Pre-oxidative amperometric glucose biosensor incorporat-ed with carbon nanotube and PbO2[J].Electrochemistry(电化学),2006,12(3):319.
[9]Cao J L,Zhao H Y,Cao F H,et al.Electrocatalytic deg-radation of4-chlorophenol on F-doped PbO2anodes[J].Electrochim Acta,2009,54:2595.
[10]Yang X P,Zou R Y,Huo F,et al.Preparation and characterization of Ti/SnO2-Sb2O3-Nb2O5/PbO2thin film as electrode material for the degradation of phenol[J].J Hazard Mater,2009,164:367.
[11]Song Y H,Wei G,Xiong R C.Structure and properties of PbO2-CeO2anodes on stainless steel[J].Electro-chim Acta,2007,52:7022.
[12]Tong S P,Ma C A,Feng H.A novel PbO2electrode preparation and its application in organic degradation[J].Electrochim Acta,2008,53:3002.
[13]Kong J T,Shi S Y,Kong L C,et al.Preparation and characterization of PbO2electrodes doped with differ-ent rare earth oxides[J].Electrochim Acta,2007,53:2048.
[14]Musiania M,Furlanetto F,Bertoncello R.Electrodepos-ited PbO2+RuO2:a composite anode for oxygen evo-lution from sulphuric acid solution[J].J Electroanal Chem,1999,465:160.
[15]Abaci S,Pekmez K,Hokelek T,et al.Investigation of some parameters influencing electro crystallisation of PbO2[J].J Power Sources,2000,88:232.
[16]Zhang Xinsheng(张新胜),Ding ping(丁平),Dai Yingchun(戴迎春),et al.Kinetic study of electrooxi-dation of benzene[J].Electrochemistry(电化学),1999,5(1):106.
[17]Rajkumar D,Palanivelu K.Electrochemical treatment of industrial wastewater[J].J Hazard Mater,2004,113:123.

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