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Abstract

The Nafion117/SiO2 composite membrane was prepared by sol-gel method.The results showed that,during composite membrane preparation process,the ratio of MeOH and TEOS did not affect the penetration rate of VO2+ basically,however,the lowest permeability of 427×10-9cm2/s in the membrane was achieved while hydrolysis time was 10 min and natural drying for 24 h after hydrolysis,which reduced by 52 times than that in Nafion117 membrane.The SEM tests proved that SiO2 grains grew bigger in the composite membrane during the natural drying,and most of the holes in Nafion117 were filled.Single cell test showed the battery power efficiency was improved by 2.7 %.

Keywords

all vanadium redox flow battery, permeability, silicon dioxide, power efficiency

Publication Date

2010-11-28

Online Available Date

2010-11-28

Revised Date

2010-11-28

Received Date

2010-11-28

References

[1]Long Fei(龙飞),Chen Jin-qing(陈金庆),Wang Bao-guo(王保国).Preparation of ion-exchange membranesfor all vanadium flow redox battery[J].Tianjin Poly-technic University(天津工业大学学报),2008,27(4):9-11.
[2]Rikukawa M,Sanui K.Proton-conducting polymer elec-trolyte membranes based on hydrocarbon polymers[J].Prog Polym Sci,2000,25(10):1463-1502.
[3]Kenenth A Mauritz,Robert B Moore.State of understan-ding of Nafion[J].Chem Rev,2004,104(10):4535-4586.
[4]Jiang S P,Liu Z C,Tian Z Q.Layer-by-layer self-assem-bly of composite polyelectrolyte-nafion membranes fordirect methanol fuel cells[J].Adv Mater,2006,18(8):1068-1072.
[5]Hickner M A,Ghassemi H,Skim Y,et al.Alternativepolymer systems for proton exchange membranes(PEMs)[J].Chem Rev,2004,104(10):4587-4611.

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