The Electrochemical Behavior of C￣(60)-chemically Modified Poly(N-vinylcarhzole)in 1 mol/L LiClO_4-THF Solutions

Authors

Yu Chen, Qinghai Education College, Qinghai,Xining 810008;
Zuen Huang, Department of Chemistry, Fudan University,Shanghai 200433;
Ruifang Cai, Department of Chemistry, Fudan University,Shanghai 200433;
Fupin Zhang, Department of Chemistry, Fudan University,Shanghai 200433;

Abstract

The electrochemical behavior of C￣(60)-PNVC copolymer in 1 mol/L LiClO_4-THF solutions has been studied by cyclic voltammetry.The results demonstrated that there are considerable differences of electronic structure between PNVC (Poly (N-vinylcarbazole )) and C￣(60)-PNVC copolymer, this being consistent with the ESR results and the oxidstion-reduction activarion of pure PNVC by C￣(60)-chemical modification. In the potential region,1.3V～-3.5V,five steps,0. 90V/0.60V,0.20V/0.00V,-1.05V/-1.30 V,-1.25V/-1.75 V,-2.00V/-2.50V, of oxidation/reduction proceases were indicated in the cyclic voltammetry for pure PNVC,whereas seven steps,0.20V/0.20V,-0.30V/-0.50 V,-0. 60V/-0.60 V,-0.80V/-1. 10 V,-1.95V/-2. 10 V,-2. 50 V/-2. 70 V,-3. 00V/-3. 00 V, of oxidation/reduction processes for the C￣(60)-PNVC copolymer were observed under the idenrical experimental condirion.

Keywords

Poly(N-vinylcarbazole), Polymer, Electrochemical behavior.

DOI Link

https://doi.org/10.61558/2993-074X.3060

Publication Date

1996-02-28

Online Available Date

1996-02-28

Revised Date

1996-02-28

Received Date

1996-02-28

Recommended Citation

Yu Chen, Zuen Huang, Ruifang Cai, Fupin Zhang. The Electrochemical Behavior of C￣(60)-chemically Modified Poly(N-vinylcarhzole)in 1 mol/L LiClO_4-THF Solutions[J]. Journal of Electrochemistry, 1996 , 2(1): Article 19.
DOI: 10.61558/2993-074X.3060
Available at: https://jelectrochem.xmu.edu.cn/journal/vol2/iss1/19

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