Abstract
The electrochemical behavior of 5,9,14,18,23,27,32,36 Octa Butyl 2,3 Naphalocyanine Manganese (Ⅲ) [(BuO) 8NPcMn(Ⅲ)Cl] in four nonaqueous solvents was studied by means of cyclic voltammetry, and the corresponding half wave potentials (E 1/2 ) of redox reactions were obtained. Four (or five) pairs of redox peaks were assigned. The solvent effect on the electrochemical characteristics of this coordination compound was also discussed preliminarily, and the electrochemical behavior of the complex was compared with that of nonsubstitued naphthalocyanine.
Keywords
Octa buty1 2, 3 naphthalocyanine manganese (Ⅲ), Electrochemistry, Nonaqeous solvents
Publication Date
1996-11-28
Online Available Date
1996-11-28
Revised Date
1996-11-28
Received Date
1996-11-28
Recommended Citation
Suling Yang, Ersheng Liu, Naisheng Chen, Jinling Huang.
Study of Electrochemistry of Octa Butyl 2, 3 Naphthalocyanine Manganese(Ⅲ) in Nonaqeous Solvents[J]. Journal of Electrochemistry,
1996
,
2(4): Article 15.
DOI: 10.61558/2993-074X.3094
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol2/iss4/15
References
1志村幸雄，志村美知子．ナフタロシアニソ色素．染料と药品，1992，37（12）：3212CookMJ，DunnAJ，HoweSD，ThomsonAJ．OctaalkoxyphthalocyanineandNaphthalocyanineDerivative；DyeswithQbandAbsorptionintheFarRedofNearInfrared．J．Chem．Soc．PerkinTrans．，1988，（1）：24533PerrinDD，ArovegoWLFandPerinDR著，时雨译，王段，长强校．实验室化学药品的提纯方法，第二版，北京：化学工业出版社．1987：53～3614AnsonF，（讲演稿）黄慰曾等编译，高晓霞，杨文治校．电化学和电分析化学．北京：北京大学出版社，1983：145LeverABP，MinorPC，WilshireJP．ElectrochemistryofManganesPhthalocyanineinNonaqueousMedin．Inorg．Chem．，1981，20：25506HanackM，RenzG，StrahleJ．SchimidSSynthesisandCharactreizationofSubstituted（1，2Naphthalocyaninate）ironCompoundsandBisaxialyCoordinatedIsocyanideComplexes．J．Org．Chem．1991，56：35017吴星，姚荣等．四苯氧基酞菁镁、锰、铝和锌的合成和性质．无机化学学报，1994，10（2）：1788OrihashiY，NishikawaM，OhnoHetal．EfectofSubstituentsonOxidationPotentialofPhthalocyaninesandElectrocrystalization．Bul，Chem．Soc．Jpn．，1987，60：3731
