Abstract
Electrochemical conversion reactions have received considerable interest as a new redox mechanism for constructing high capacity electrodes of rechargeable batteries. Without strict restrictions on the crystalline structure of the host lattice and the size of the associated ions, conversion reactions can take place in a variety of different metal compounds with different metal cations and deliver much higher reversible capacities through full utilization of all the oxidation states of the transition-metal compounds, opening up a new avenue for developing high capacity materials of rechargeable batteries. This paper briefly reviews the state of the art and challenges of conversion electrodes and also discusses the possible strategies for realizing high efficient electrochemical conversions and for establishing advanced Li-ion and Na-ion batteries.
Graphical Abstract
Keywords
electrochemical conversion reactions, lithium ion batteries, sodium ion batteries
Publication Date
2015-04-28
Online Available Date
2015-01-31
Revised Date
2015-01-27
Received Date
2014-11-17
Recommended Citation
Ting LI, Han-xi YANG.
Electrochemical Conversion Reactions and Their Applications for Rechargeable Batteries[J]. Journal of Electrochemistry,
2015
,
21(2): 115-122.
DOI: 10.13208/j.electrochem.141047
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol21/iss2/2
References
[1]Cabana J, Monconduit L, Larcher D, et al. Beyond intercalation-based Li-ion batteries: The state of the art and challenges of electrode materials reacting through conversion reactions[J]. Advanced Materials, 2010, 22(35): E170-E192.
[2]Gao X P, Yang H X. Multi-electron reaction materials for high energy density batteries[J]. Energy & Environmental Science, 2010, 3(2): 174-189.
[3]Kim S W, Seo D H, Ma X H, et al. Electrode materials for rechargeable sodium-ion batteries: Potential alternatives to current lithium-ion batteries[J]. Advanced Energy Materials, 2012, 2(7): 710-721.
[4]Armand M, Tarascon J M. Building better batteries[J]. Nature, 2008, 451(7179): 652-657.
[5]Poizot P, Laruelle S, Grugeon S, et al. Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries[J]. Nature, 2000, 407(6803): 496-499.
[6]Chen Z X, Zhou M, Cao Y L, et al. In situ generation of few-layer graphene coatings on SnO2-SiC core-shell nanoparticles for high-performance lithium-ion storage[J]. Advanced Energy Materials, 2012, 2(1): 95-102.
[7]Souza D C S, Pralong V, Jacobson A J, et al. A reversible solid-state crystalline transformation in a metal phosphide induced by redox chemistry[J]. Science, 2002, 296(5575): 2012-2015.
[8]Gillot F, Monconduit L, Doublet M L. Electrochemical behaviors of binary and ternary manganese phosphides[J]. Chemistry of Materials, 2005, 17(23): 5817-5823.
[9]Boyanov S, Bernardi J, Gillot F, et al. FeP: Another attractive anode for the Li-ion battery enlisting a reversible two-step insertion/conversion process[J]. Chemistry of Materials, 2006, 18(15): 3531-3538.
[10]Qian J F, Qiao D, Ai X P, et al. Reversible 3-Li storage reactions of amorphous phosphorus as high capacity and cycling-stable anodes for Li-ion batteries[J]. Chemical Communications, 2012, 48: 8931-8933.
[11]Li H, Balaya P, Maier J. Li-storage via heterogeneous reaction in selected binary metal fluorides and oxides[J]. Journal of The Electrochemical Society, 2004, 151(11): A1878-A1885.
[12]Li H, Richter G, Maier J. Reversible formation and decomposition of LiF clusters using transition metal fluorides as precursors and their application in rechargeable Li batteries[J]. Advanced Materials, 2003, 15(9): 736-739.
[13]Badway F, Cosandey F, Pereira N, et al. Carbon metal fluoride nanocomposites high-capacity reversible metal fluoride conversion materials as rechargeable positive electrodes for Li batteries[J]. Journal of The Electrochemical Society, 2003, 150(10): A1318-A1327.
[14]Li T, Li L, Cao Y L, et al. Reversible three-electron redox behaviors of FeF3 nanocrystals as high-capacity cathode-active materials for Li-ion batteries[J]. The Journal of Physical Chemistry C, 2010, 114(7), 3190-3195.
[15]Li C, Gu L, Tsukimoto S, et al. Low-temperature ionic-liquid-based synthesis of nanostructured iron-based fluoride cathodes for lithium batteries[J]. Advanced Materials, 2010, 22(33): 3650-3654.
[16]Kim S W, Seo D H, Gwon H, et al. Fabrication of FeF3 nanoflowers on CNT branches and their application to high power lithium rechargeable batteries[J]. Advanced Materials, 2010, 22(46): 5260-5264.
[17]Liu J L, Cui W J, Wang C X, et al. Electrochemical reaction of lithium with CoCl2 in nonaqueous electrolyte[J]. Electrochemistry Communications, 2011, 13(3): 269-271.
[18]Li T, Chen Z X, Ai X P, et al. Transition-metal chlorides as conversion cathode materials for Li-ion batteries[J]. Electrochimca Acta, 2012, 68: 202-205.
[19]Débart A, Dupont L, Patrice R, et al. Reactivity of transition metal (Co, Ni, Cu) sulphides versus lithium: The intriguing case of the copper sulphide[J]. Solid State Sciences, 2006, 8(6): 640-651.
[20]Li T, Ai X P, Yang H Y. Reversible electrochemical conversion reaction of Li2O/CuO nanocomposites and their application as high-capacity cathode materials for Li-ion batteries[J]. The Journal of Physical Chemistry C, 2011, 115(13): 6167-6174.
[21]Nishijima M, Gocheva I D, Okada S, et al. Cathode properties of metal trifluorides in Li and Na secondary batteries[J]. Journal of Power Sources, 2009, 190(2): 558-562.
[22]Li C, Yin C, Mu X, et al. Top-down synthesis of open framework fluoride for lithium and sodium batteries[J]. Chemistry of Materials, 2013, 25(6): 962-969.
[23]Li C, Yin C, Gu L, et al. An FeF3·0.5H2O polytype: A microporous framework compound with intersecting tunnels for Li and Na batteries[J]. Journal of the American Chemical Society, 2013, 135(31): 11425-11428.
[24]Li T(李婷), Chen Z(陈重学), Cao Y(曹余良), et al. NaF-M (M=Fe, Cu) nanocomposites as conversion cathode materials for sodium ion batteries[J]. Journal of Electrochemistry(电化学), 2012, 18(4): 291-294.
[25]Hariharan S, Saravanan K, Ramar V, et al. A rationally designed dual role anode material for lithium-ion and sodium-ion batteries: Case study of eco-friendly Fe3O4[J]. Physical Chemistry Chemical Physics, 2013, 15(8): 2945-2953.
[26]Wen J W, Zhang D W, Zang Y, et al. Li and Na storage behavior of bowl-like hollow Co3O4 microspheres as an anode material for lithium-ion and sodium-ion batteries[J]. Electrochimica Acta, 2014, 132: 193-199.
[27]Raju V, Rains J, Gates C, et al. Superior cathode of sodium-ion batteries: Orthorhombic V2O5 nanoparticles generated in nanoporous carbon by ambient hydrolysis deposition[J]. Nano Letters, 2014, 14(7): 4119-4124.
[28]Wang L, Zhang K, Hu Z, et al. Porous CuO nanowires as the anode of rechargeable Na-ion batteries[J]. Nano Research, 2014, 7(2): 199-208.
[29]Valvo M, Lindgren F, Lafont U, et al. Towards more sustainable negative electrodes in Na-ion batteries via nanostructured iron oxide[J]. Journal of Power Sources, 2014, 245: 967-978.
[30]Yu D Y W, Prikhodchenko P V, Mason C W, et al. High-capacity antimony sulphide nanoparticle-decorated graphene composite as anode for sodium-ion batteries[J]. Nature Communications, 2013, 4: 2922.
[31]Qu B, Ma C, Ji G, et al. Layered SnS2-reduced graphene oxide composite a high-capacity, high-rate, and long-cycle life sodium-ion battery anode material[J]. Advanced Materials, 2014, 26(23): 3854-3859.
[32]Wu L, Lu H, Xiao L, et al. A tin(II) sulfide-carbon anode material based on combined conversion and alloying reactions for sodium-ion batteries[J]. Journal of Materials Chemistry A, 2014, 2(39): 16424-16428.
[33]Qian J, Xiong Y, Cao Y, et al. Synergistic Na-storage reactions in Sn4P3 as a high-capacity, cyclestable anode of Na-ion batteries[J]. Nano Letters, 2014, 14(4): 1865-1869.
[34]Fullenwarth J, Darwiche A, Soares A, et al. NiP3: A promising negative electrode for Li- and Na-ion batteries[J]. Journal of Materials Chemistry A, 2014, 2(7): 2050-2059.
Included in
Engineering Science and Materials Commons, Materials Chemistry Commons, Materials Science and Engineering Commons, Physical Chemistry Commons, Power and Energy Commons
