Influences of Morphology and Nitrogen Doping on the Electrocatalytic Characteristics for Oxygen Reduction Reaction of NiO/rGO

Authors

Dong LIANG, Shandong Provincial Key Laboratory of Fluorine Chemistry Material, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China;
Heng-yi FANG, Shandong Provincial Key Laboratory of Fluorine Chemistry Material, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China;
Shuo YAO, Shandong Provincial Key Laboratory of Fluorine Chemistry Material, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China;
Jie-mei YU, Shandong Provincial Key Laboratory of Fluorine Chemistry Material, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China;
Zhao-liang ZHANG, Shandong Provincial Key Laboratory of Fluorine Chemistry Material, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China;
Zhan-kun JIANG, Shandong Provincial Key Laboratory of Fluorine Chemistry Material, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China;
Xue-ping GAO, School of Materials Science and Engineering, Shandong University, Jinan 250061, China;
Tai-zhong HUANG, Shandong Provincial Key Laboratory of Fluorine Chemistry Material, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China;Follow

Corresponding Author

Tai-zhong HUANG(chm_huangtz@ujn.edu.cn)

Abstract

In this research, the reduced graphene oxide (rGO) supported sheet-like NiO (NiO/rGO) and spherical-like NiO (NiO/N-rGO) catalysts for oxygen reduction reaction (ORR) were prepared. The structures, morphologies and chemical states of the two catalysts were characterized by X-ray diffraction (XRD), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The electrochemical catalytic performance of the two catalysts for ORR were investigated by cyclic voltammetry (CV), Tafel, linear sweeping voltammetry (LSV), rotating disc electrode (RDE) and rotating ring disc electrode (RRDE) tests. Electrochemical results showed that the current density and onset potential (about 0.89 V) of nitrogen doped rGO (N-rGO) supported spherical-like NiO were close to those of commercial Pt/C(20%) catalysts. RDE and RRDE data proved that the ORR happened mainly through 4-electron route in an alkaline electrolyte with both catalysts. The spherical-like NiO/N-rGO catalyst showed great promise as alternative for Pt-based catalyst.

Graphical Abstract

Keywords

nickel oxide, nitrogen doping, morphology, catalyst, oxygen reduction reaction

DOI Link

https://doi.org/10.13208/j.electrochem.181145

Publication Date

2019-10-28

Online Available Date

2019-02-01

Revised Date

2019-01-21

Received Date

2018-12-20

Recommended Citation

Dong LIANG, Heng-yi FANG, Shuo YAO, Jie-mei YU, Zhao-liang ZHANG, Zhan-kun JIANG, Xue-ping GAO, Tai-zhong HUANG. Influences of Morphology and Nitrogen Doping on the Electrocatalytic Characteristics for Oxygen Reduction Reaction of NiO/rGO[J]. Journal of Electrochemistry, 2019 , 25(5): 589-600.
DOI: 10.13208/j.electrochem.181145
Available at: https://jelectrochem.xmu.edu.cn/journal/vol25/iss5/7

References

[1] Service R F. Shrinking fuel cells promise power in your pocket[J]. Science, 2002, 296(5571): 1222-1224.
[2] Winter M, Brodd R J. What are batteries, fuel cells, and supercapacitors?[J]. Chemical Reviews, 2004, 104: 4245-4270.
[3] Ji X, Lee K T, Holden R, et al. Nanocrystalline intermetallics on mesoporous carbon for direct formic acid fuel cell anodes[J]. Nature Chemistry, 2010, 2(4): 286.
[4] Gong K P, Du F, Xia Z H, et al. Nitrogen-doped carbon nanotube arrays with high electrocatalytic activity for oxygen reduction[J]. Science, 2009, 323(5915): 760-764.
[5] Rahul R, Singh R K, Neergat M. Effect of oxidative heat-treatment on electrochemical properties and oxygen reduction reaction (ORR) activity of Pd-Co alloy catalysts[J]. Journal of Electroanalytical Chemistry, 2014, 712(5): 223-229.
[6] Ferrero G A, Fuertes A B, Sevilla M, et al. Efficient metal-free N-doped mesoporous carbon catalysts for ORR by a template-free approach[J]. Carbon, 2016, 106: 179-187.
[7] Zhu C Z, Dong S J. Recent progress in graphene-based nanomaterials as advanced electrocatalysts towards oxygen reduction reaction[J]. Nanoscale, 2013, 5(5): 1753-1767.
[8] Morozan A, Jousselme B, Palacin S. Low-platinum and platinum-free catalysts for the oxygen reduction reaction at fuel cell cathodes[J]. Energy & Environmental Science, 2011, 4(4): 1238-1254.
[9] Compton O C, Nguyen S B T. Graphene oxide, highly reduced graphene oxide, and graphene: Versatile building blocks for carbon-based materials[J]. Small, 2010, 6(6): 711-723.
[10] Lee W, Suzuki S, Miyayama M. Electrochemical properties of poly (anthraquinonyl sulfide)/graphene sheets composites as electrode materials for electrochemical capacitors[J]. Nanomaterials, 2014, 4(3): 599-611.
[11] Dai L M. Graphene: tunable superdoping[J]. Nature Energy, 2016, 1(4): 16041.
[12] Xiu L Y(修陆洋)，Yu M Z(于梦舟)，Yang P J(杨鹏举)，et al. Caging porous Co-N-C nanocomposites in 3D graphene as active and aggregation-resistant electrocatalyst for oxygen reduction reaction[J]. Journal of Electrochemistry(电化学), 2018, 24(6): 715-725.
[13] Bayram E, Yilmaz G, Mukerjee S. A solution-based procedure for synthesis of nitrogen doped graphene as an efficient electrocatalyst for oxygen reduction reactions in acidic and alkaline electrolytes[J]. Applied Catalysis B: Environmental, 2016, 192: 26-34.
[14] Li L, Wang M K, Cui N, et al. CeO₂ doped Pt/C as an efficient cathode catalyst for an air-cathode single-chamber microbial fuel cell[J]. RSC Advances, 2016, 6(31): 25877-25881.
[15] Yu J M, Liu Z M, Zhai L M, et al. Reduced graphene oxide supported TiO₂ as high performance catalysts for oxygen reduction reaction[J]. International Journal of Hydrogen Energy, 2016, 41(5): 3436-3445.
[16] Cao S Y, Han N, Han J, et al. Mesoporous hybrid shells of carbonized polyaniline/Mn₂O₃ as non-precious efficient oxygen reduction reaction catalyst[J]. ACS Applied Materials & Interfaces, 2016, 8(9): 6040-6050..
[17] Hummers Jr W S, Offeman R E. Preparation of graphitic oxide[J]. Journal of the American Chemical Society, 1958, 80(6): 1339-1339.
[18] Mignuzzi S, Kumar N, Brennan B, et al. Probing individual point defects in graphene via near-field Raman scattering[J]. Nanoscale, 2015, 7(46): 19413-19418.
[19] Wang Y R, Wei H G, Lu Y, et al. Multifunctional carbon nanostructures for advanced energy storage applications[J]. Nanomaterials, 2015, 5(2): 755-777.
[20] Jiang M X(姜孟秀), Zhang J(张晶), Li Y H(李月华), et al. Cobalt-based nitrogen-doped carbon non-noble metal catalysts for oxygen reduction reaction[J]. Journal of Electrochemistry(电化学), 2017, 23(6): 627-637..
[21] Qian X F, Li B, Hu Y Y, et al. Exploring meso-/microporous composite molecular sieves with core-shell structures[J]. Chemistry - A European Journal, 2012, 18(3): 931-939.
[22] Guo Z Y, Jiang C C, Teng C, et al. Sulfur, trace nitrogen and iron codoped hierarchically porous carbon foams as synergistic catalysts for oxygen reduction reaction[J]. ACS Applied Materials & Interfaces, 2014, 6(23): 21454-21460.
[23] Wang H B, Maiyalagan T, Wang X. Review on recent progress in nitrogen-doped graphene: synthesis, characterization, and its potential applications[J]. ACS Catalysis, 2012, 2(5): 781-794.
[24] Liang J, Jiao Y, Jaroniec M, et al. Sulfur and nitrogen dual-doped mesoporous graphene electrocatalyst for oxygen reduction with synergistically enhanced performance[J]. Angewandte Chemie International Edition, 2012, 51(46): 11496-11500.
[25] Lee W J, Maiti U N, Lee J M, et al. Nitrogen-doped carbon nanotubes and graphene composite structures for energy and catalytic applications[J]. Chemical Communications, 2014, 50(52): 6818-6830.
[26] Wang Y, Shao Y, Matson D W, et al. Nitrogen-doped graphene and its application in electrochemical biosensing[J]. ACS Nano, 2010, 4(4): 1790-1798.
[27] Zhou W J, Zhou J, Zhou Y C, et al. N-doped carbon-wrapped cobalt nanoparticles on N-doped graphene nanosheets for high-efficiency hydrogen production[J]. Chemistry of Materials, 2015, 27(6): 2026-2032.
[28] Zhang W Y, Wu L F, Li Z L, et al. Doped graphene: synthesis, properties and bioanalysis[J]. RSC Advances, 2015, 5(61): 49521-49533.
[29] Peck M A, Langell M A. Comparison of nanoscaled and bulk NiO structural and environmental characteristics by XRD, XAFS, and XPS[J]. Chemistry of Materials, 2012, 24(23): 4483-4490.
[30] Byon H R, Suntivich J, Shao-Horn Y. Graphene-based non-noble-metal catalysts for oxygen reduction reaction in acid[J]. Chemistry of Materials, 2011, 23(15): 3421-3428.
[31] Soriano L, Preda I, Gutié A, et al. Surface effects in the Ni 2p, X-ray photoemission spectra of NiO[J]. Physical Review B, 2007, 75(23): 2288-2288.
[32] Rodríguez J L, Valenzuela M A, Poznyak T, et al. Reactivity of NiO for 2, 4-D degradation with ozone: XPS studies[J]. Journal of Hazardous Materials, 2013, 262: 472-481.
[33] Cheng Y, Pan J, Saunders M, et al. Structurally confined ultrafine NiO nanoparticles on graphene as a highly efficient and durable electrode material for supercapacitors[J]. RSC Advances, 2016, 6(56): 51356-51366.
[34] Wang Y L, Zhang D D, Tang M, et al. Electrocatalysis of gold nanoparticles/layered double hydroxides nanocomposites toward methanol electro-oxidation in alkaline medium[J]. Electrochimica Acta, 2010, 55(12): 4045-4049.
[35] Huang T Z, Yu J M, Han J T, et al. Oxygen reduction catalytic characteristics of vanadium carbide and nitrogen doped vanadium carbide[J]. Journal of Power Sources, 2015, 300: 483-490.
[36] Zecevic S K, Wainright J S, Litt M H, et al. Kinetics of O₂ reduction on a Pt electrode covered with a thin film of solid polymer electrolyte[J]. Journal of the Electrochemical Society, 1998, 145(9): 3308-3311.
[37] Zhang J T, Xia Z H, Dai L M. Carbon-based electrocatalysts for advanced energy conversion and storage[J]. Science Advances, 2015, 1(7): 362-367.
[38] Paulus U A, Schmidt T J, Gasteiger H A, et al. Oxygen reduction on a high-surface area Pt/Vulcan carbon catalyst: a thin-film rotating ring-disk electrode study[J]. Journal of Electroanalytical Chemistry, 2001, 495(2): 134-145.
[39] Chen M, Hou C J, Huo D Q, et al. An electrochemical DNA biosensor based on nitrogen-doped graphene/Au nanoparticles for human multidrug resistance gene detection[J]. Biosensors and Bioelectronics, 2016, 85: 684-691.