Abstract
It is necessary to develop an inexpensive catalyst for the replacement of precious metal catalysts (such as RuO2, IrO2). In this article, the metal organic framework ZIF-67 was synthesized by solvothermal method at room temperature, and then the high temperature carbonization was used to prepare the nitrogen-doped carbon-based composite material Co@NC with the Co nanoparticle inside. The effects of the carbonization temperature on surface morphology, chemcial composition and electrocatalytic property were investigated. Most importantly, the Co@NC catalyst with the best morphology and structure was synthesized, and its catalytic activity and stability toward oxygen evolution reaction (OER) were studied under alkaline conditions. Electrochemical test results showed that the Co@NC catalyst prepared at 700 ℃ had higher OER catalytic activity and excellent stability. It only required an overpotential of 266 mV for reaching the current density of 10 mA·cm-2, with good stability over 40 h.
Graphical Abstract
Keywords
ZIF-67, Co@NC, nanocomposites, electrocatalytic properties
Publication Date
2019-10-28
Online Available Date
2019-10-28
Revised Date
2019-08-10
Received Date
2019-05-06
Recommended Citation
Xiao-li TAN, Deng-hong HE, Xing-wang ZHANG.
Preparations and Electrochemical Properties of Co@NC Nanocomposites Based on ZIF-67[J]. Journal of Electrochemistry,
2019
,
25(5): 601-607.
DOI: 10.13208/j.electrochem.181146
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol25/iss5/8
References
[1] Graeme G, Jafar A, Danilovic N, et al. Structural basis for differing electrocatalytic water oxidation by the cubic, layered and spinel forms of lithium cobalt oxides[J]. Energy & Environmental Science, 2016, 9(1): 184-192.
[2] Armaroli N, Balzani V. The future of energy supply: Challenges and opportunities[J]. Angewandte Chemie International Edition ,2007, 46(1/2): 52-66.
[3] Marinescu S C, Winkler J R, Gray H B. Molecular mechanisms of cobalt-catalyzed hydrogen evolution[J]. Proceedings of the National Academy Sciences of the United States of America, 2012, 109(38): 15127-15131.
[4] Yang Y, Fei H L, Ruan G D, et al. Porous cobalt-based thin film as a bifunctional catalyst for hydrogen generation and oxygen generation[J]. Advanced Materials, 2015, 27(20): 3175-3180.
[5] Carmo M, Fritz D L, Mergel J, et al. A comprehensive review on PEM water electrolysis[J]. International Journal of Hydrogen Energy, 2013, 38 (12): 4901-4934.
[6] Jin Z Y, Li P P, Huang X, et al. Three-dimensional amorphous tungsten-doped nickel phosphide microsphere as an efficient electrocatalyst for hydrogen evolution[J]. Journal of Materials Chemistry A, 2014, 2(43): 18593-18599.
[7] Katsounaros I, Cherevko S, Zeradjanin A R, et al. Oxygen electrochemistry as a cornerstone for sustainable energy conversion[J]. Angewandte Chemie International Edition, 2014, 53(1): 102-121.
[8] Frydendal R, Paoli E A, Knudsen B P, et al. Benchmarking the stability of oxygen evolution reaction catalysts: the importance of monitoring mass losses[J]. ChemElectroChem, 2014, 1(12): 2075-2081.
[9] Zhou T H, Du Y H, Wang D P, et al. Phosphonate-based metal-organic framework derived Co-P-C hybrid as an efficient electrocatalyst for oxygen evolution reaction[J]. ACS Catalysis, 2017, 7(9): 6000-6007.
[10] Tian J, Morozan A, Sougrati M T, et al. Optimized synthesis of Fe/N/C cathode catalysts for PEM fuel cells: a matter of iron-ligand coordination strength[J]. Angewandte Chemie International Edition, 2013, 52(27): 6867-6870.
[11] Xu K, Chen P Z, Li X L, et al. Metallic nickel nitride nanosheets realizing enhanced electrochemical water oxidation[J]. Journal of American Chemical Society, 2015, 137(12): 4119-4125.
[12] Chen P Z, Xu K, Fang Z W, et al. Metallic CO4N porous nanowire arrays activated by surface oxidation as electrocatalysts for the oxygen evolution reaction[J]. Angewandte Chemie International Edition, 2015, 54(49): 14710-14714.
[13] Peng Z, Jia D S, Al-Enizi A M, et al. From water oxidation to reduction: homologous Ni-Co based nanowires as complementary water splitting electrocatalysts[J]. Advanced Energy Materials, 2015, 5(9): 1402031.
[14] Zhang S L, Guan B Y, Lou X W. Co-Fe alloy/n-doped carbon hollow spheres derived from dual metal-organic frameworks for enhanced electrocatalytic oxygen reduction[J]. Small, 2019, 15(13): 1805324.
[15] Chen K, Sun Z H, Fang R P, et al. Metal-organic frameworks (MOFs)-derived nitrogen-doped porous carbon anchored on graphene with multifunctional effects for lithium-sulfur batteries[J]. Advanced Functional Materials, 2018, 28(38): 1707592.
[16] Wang X X, Hwang S Y, Pan Y T, et al. Ordered Pt3Co intermetallic nanoparticles derived from metal-organic frameworks for oxygen reduction[J]. Nano Letters, 2018, 18(7): 4163-4171.
[17] Li X Z, Fang Y Y, Lin X Q, et al. MOF derived Co3O4 nanoparticles embedded in N-doped mesoporous carbon layer/MWCNT hybrids:extraordinary bi-functional electrocatalysts for OER and ORR[J]. Journal of Materials Chemistry A, 2015, 3(33): 17392-17402.
[18] Zhao Y, Yang L J, Chen S, et al. Can boron and nitrogen co-doping improve oxygen reduction reaction activity of carbon nanotubes[J]. Journal of American Chemical Society, 2013, 135(4): 1201-1204.
[19] Wang S Y, Iyyamperumal E, Roy A, et al. Vertically aligned BCN nanotubes as efficient metal-free electrocatalysts for the oxygen reduction reaction:a synergetic effect by co-doping with boron and nitrogen[J]. Angewandte Chemie International Edition, 2011, 50(49): 11756-11760.
[20] Zhang J T, Zhao Z H, Xia Z H, et al. A metal-free bifunctional electrocatalyst for oxygen reduction and oxygen evolution reactions[J]. Nature Nanotechnology, 2015, 10(5): 444-452.
[21] Aijaz A, Masa J, Rosler C, et al. Co@Co3O4 encapsulated in carbon nanotube-grafted nitrogen-doped carbon polyhedra as an advanced bifunctional oxygen electrode[J]. Angewandte Chemie International Edition, 2016, 55(12): 4087-4091.
[22] Wang R, Cao J Y, Cai S C, et al. MOF@cellulose derived Co-N-C nanowire network as an advanced reversible oxygen electrocatalyst for rechargeable zinc-air batteries[J]. ACS Applied Energy Materials, 2018, 1(3): 1060-1068.
[23] Gadipelli S, Zhao, T T, Shevlin S A, et al. Switching effective oxygen reduction and evolution performance by controlled graphitization of a cobalt-nitrogen-carbon framework system[J]. Energy & Environmental Science, 2016, 9(5): 1661-1667.
[24] Yuan Y F, Chen F, Ye L W, et al. Construction of Co3O4@TiO2 heterogeneous mesoporous hollow nano-cage-in-nanocage from metal-organic frameworks with enhanced lithium storage properties[J]. Journal of Alloys and Compounds, 2019, 790(3): 814-821.
[25] Xie Z Q, Wang Y. Facile synthesis of MOF-derived Co@CoNx/bamboo-like carbon tubes for efficient electrocatalytic water oxidation[J]. Electrochimica Acta, 2019, 296(5): 372-378.
