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Corresponding Author

Xiaoyou Yuan

Abstract

A new type evolution hydrogen electrode NiS(N) has been made from nickel plating electrode in NiSO4CS(NH2)2 bath by electrodeposition. It is analyzed by SEM and Xray energy spectrum. The NiS(N) electrode is different from the NiS(O) electrode (which is used in plant at present time) in surface metallograph configuration and surfer content. The results of measurement polarization curves and water electrolysis 480 hours at 5 000 A·m-2 show that the evolution hydrogen overpotential of NiS(N) electrode is decreased at least 160 mV relative to NiS(O) electrode and the stablisum of NiS(N) electrode is better than that of NiS(O) electrode.

Publication Date

1997-11-28

Online Available Date

1997-11-28

Revised Date

1997-11-28

Received Date

1997-11-28

References

1HartmutWendt,Nineyearsofresearchanddevelopmentonadvancedwaterelectrolysis.AreviewoftheresearchprogrammeoftheCommissionoftheEuropeanCommunities.J.Appl.Electrochem.,1988,18:1~142查全性.电极过程动力学导论.北京:科学出版社,1976:1283安特罗波夫L.I.著,吴仲达等译.理论电化学.北京:高教出版社,1982:42

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