Abstract
New cell designs for simultaneous electrochemical(EC) and electron spin resonance (ESR) measurements are reported for coaxial microwave cavity. Adjustable shieldings are introduced so that the working electrode can be much shorter than the full height of the cavity. Besides the traditional helical electrode, the working electrode can be cylinders made from metal plates, metallic meshes or even composite materials. The counter electrode can be placed either inside or outside the cavity. These features make the new designs more flexible than that previously reported. With a nonperforated cylindrical electrode, this cell can be used to determine the standard potential and the number of electrons of electrode reactions involving radicals. Other possible applications are also briefed.
Publication Date
1998-05-28
Online Available Date
1998-05-28
Revised Date
1998-05-28
Received Date
1998-05-28
Recommended Citation
Lin Lu Juntao Zhuang.
New ESRElectrochemical Cell Designs for Coaxial Microwave Cavity[J]. Journal of Electrochemistry,
1998
,
4(2): 189-198.
DOI: 10.61558/2993-074X.1360
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol4/iss2/4
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