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Corresponding Author

Junxiang He

Abstract

Synthesis of butyl butyrate by direct electroxidation of n butyl alcohol and the electrochemical behaviors of several selected conducting oxide electrodes (Pb/PbO 2、Ti/PbO 2、i/SnO 2 +Sb 2O 3 /PbO 2 and Ti/SnO 2+Sb 2O 3+PdO x/PbO 2) have been investigated. The results demonstrated that the intermediate layers of SnO 2、Sb 2O 3 and PdO x could significantly decrease the interfacial resistance of the electrodes,and that the Ti/SnO 2+Sb 2O 3+PdO x/PbO 2 electrode possessed better electrocatelytic performance than others.

Keywords

Conducting oxide electrode, Electrocatlysis, Butyl butyrate

Publication Date

1998-11-28

Online Available Date

1998-11-28

Revised Date

1998-11-28

Received Date

1998-11-28

References

1于伯章,李毅,李青等.丁醇电解直接合成丁酸丁酯的研究.化学世界,1994,36(4):1832金世雄,朱荣昭等.二氧化铅电极镀制及其应用.南开大学学报(自然版),1984,1:863王岚,金世雄,钛基氧化物电极的性能及电化学行为.应用化学,1993,10(3):354陈康宁编著,金属阳极.上海:华东师出版社,1989,1705梁镇海,王森,孙彦平等.Ti/SnO2+Sb2O3/PbO2阳极的性能研究.电化学,1995,1(4):456

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