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Abstract

A reaction kinetic study for electrochemical oxidation of benzene was performed on a PbO 2 rotating disk electrode in 1 mol/L H 2SO 4 aqueous solution. The reaction orders, the activation energies and transfer coefficient were measured, and the kinetic expression was obtained.

Publication Date

1999-02-28

Online Available Date

1999-02-28

Revised Date

1999-02-28

Received Date

1999-02-28

References

1ClarkeJ,EhigamusoeRE,KuhnAT.Theanodicoxidationofbenzene,tolueneandanisole,J.Electroanal.Chem.,1976,70,3332ItoS,SasakiK,MurakamiY.Mechanismofformationofmaleicacidbyanodicoxidationofbenzene.DenkiKagaku,1972,40(10):7333FleszarB,PloszynskaJ.Anatempttodefinebenzeneandphenolelectrochemicaloxidationmechanism.ElectrochimicaActa,1985,30(1):314ItoS,KatayamaR,KunaiAetal.Anovelpairedelectrosynthesisofp_benzoquinoneandhydroquinonefrombenzene.TetrahedronLeters1989,30(2):2055ItoS,IwataM,SasakiK.Duetelectrosynthesisofp_benzoquinonefrombenzene.Tetrahedron,1991,47(4/5):8416陈康宁.金属阳极,第1版.上海:华东师范大学出版社,1989,146~1537周伟舫.电化学测量,第1版.上海:上海科学技术出版社,1982,177~1818OlomanC,ReilyP.Modelingandparameterestimationforafixed_bedelectrochemicalreactor.J.Electrochem.Soc.,1987,134(3):8599BardAJ,FaulknerLR著,谷林钅英等译.电化学方法,第1版.北京:化学工业出版社,1986,113

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