•  
  •  
 

Abstract

The adsorption behavior of amino acids, such as L_cysteine, histidine and arginine at gold_quartz crystal microbalance (Au_QCM) was investigated. The adsorption quantity of cysteine is more appreciable than others because of the stronger interaction between its thiol group and the gold electrode surface. The electron_transfer process of superoxide dismutase(SOD) in presence of cysteine at Au_QCM has also been studied using the electrochemical quartz crystal microbalance (EQCM) technique which reveals clearly the quasi_reversible electron_transfer process accompanied by the frequency shift cycle. The reversible adsorption and disorption processes are discussed.

Publication Date

2000-05-28

Online Available Date

2000-05-28

Revised Date

2000-05-28

Received Date

2000-05-28

References

[1] J.A .J.Brunink ,C .DiNatale ,G .Ferri,etal.Theapplicationofmetalloporphyrinsascoatingmaterialforquartzmicrobalance_basedchemicalsensors[J].Analyticachimicaacta ,1996 ,32 5 :5 3.

[2 ] R .Zhou ,U .Weimar,W .Gopel,etal.Silicon_contaningmonomers,oligomersandpolymersassensitivecoatingsforthedetectionoforganicsolventvapors[J].SensorsandActuatorsB ,1995 ,2 6 - 2 7:12 1.

[3] MarkR .Deakin ,DanielA .Buttry ,Electrochemicalapplicationsofthequartzcrystalmicrobalance[J].AnalChem ,1989,6 1(2 0 ) :1147A .

[4 ] XieQinji,YaoShouzuo .Theapplicationsofpiezoelectriccrystalsensorsonelectrochemicalresearch[J].ChemicalSensors(Chinese) ,1994,14(3) :180 .

[5 ] JamesS .Gordon ,DennisC .Johnson .Applicationofanelectrochemicalquartzcrystalmicrobalancetoastudyofwateradsorptionatgoldsurfacesinacidicmedia[J].J .Electroanal.Chem .,1994,36 5 :2 6 7.

[6 ] Z .Jusys ,G .Stalnionis ,E .Juzeliunas,etal.ThekineticH/Disotopeeffectinelectrolesscopperplating .AnEQCMstudy[J].ElectrochimicaActa ,1998,43:30 1.

[7] ZenonasJusys,StanleyBruckenstein .Electrochemicalquartzcrystalmicrogravimetryofgoldinperechloricandsulfuricacidsolution[J].ElectrochemicalandSolid_stateLetters,1998,1(2 ) :74.

[8] XiaqinWu ,XiaoyunMeng ,ZongrangZhang ,etal.,Studyondirectelectrochemicalreactionofsuperoxidedismutase[J].BioelectrochemandBioenerg .,1999,48(1) :2 2 7.

[9] WuXiaqin ,MengXiaoyun ,ZhangZongrang ,etal.Theelectrochemicalbehaviorsofsuperoxidedismutaseatpromote_modifiedgoldelectrode[J].Electrochemistry(Chinese) ,1999,5 (4) :2 7.

[10 ] WuXiaqin ,LiuQian ,ZhangZongrang ,etal.Electrochemicalbehaviorofsuperoxidedismutaseongoldminigridwiththin_layercell[J].Electrochemistry(Chinese) ,1997,3(2 ) :136 .

[11] WuXiaqin ,MengXiaoyun ,ZhangZongrang ,etal.Studyontheelectrontransferprocessofsuperoxidedis mutaseatcysteine_modifiedgoldelectrode[J].Chem .Lett.,1999,12 :12 71.

[12 ] CaoXiaowei,MengXiaoyun ,ZhangZongrang ,etal.In_situramanspectroscopicstudyontheelectrochemi calbehavoirsofSODontheL_cysteinemodifiedgoldelectrode[J].ChineseJ.LightScattering(Chinese) ,1999,11(4) :30 .

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.