A study of the Adsorption Behaviors on the Surface of Gold electrode by In-situ Electrochemical Raman Spectroscopy

Authors

Xia qin WU, Dept. of Chem., Zhangzhou Nornal College, Zhangzhou 363000) CHEN Sheng?pei, ZHOU Zhi?you, ZHEN Chun?hua,SUN Shi?gang  (State Key Lab. for Phys. Chem. of Solid Surfaces, Dept. of Chem., Xiamen Univ., Xiamen 361005,China;
Xiao wei CAO, Dept. of Chem., Shanghai Teachers Univ., Shanghai 200234 China;
Zhe su WANG, Dept. of Chem., Shanghai Teachers Univ., Shanghai 200234 China;
Xiao-yun MENG, Dept. of Chem., Shanghai Teachers Univ., Shanghai 200234 China;
Zong-rang ZHANG, Dept. of Chem., Shanghai Teachers Univ., Shanghai 200234 China;

Corresponding Author

Zong rang ZHANG

Abstract

The results of in situ measurements with Raman spectroelectrochemical thchnique on bare gold electrode and adenine modified gold electrode were reported. The adsorption behaviors of adenine and superoxide dismutase(SOD) and their interactions with gold electrode were analyed. The mechanism of promoted electron transfer process of SOD in the presence of adenine at gold electrode surface is discussed.

Keywords

In situ Raman spectroelectrochemistry, Superoxide dismutase, Adenine

DOI Link

https://doi.org/10.61558/2993-074X.1403

Publication Date

2000-11-28

Online Available Date

2000-11-28

Revised Date

2000-11-28

Received Date

2000-11-28

Recommended Citation

Xia qin WU, Xiao wei CAO, Zhe su WANG, Xiao-yun MENG, Zong-rang ZHANG. A study of the Adsorption Behaviors on the Surface of Gold electrode by In-situ Electrochemical Raman Spectroscopy[J]. Journal of Electrochemistry, 2000 , 6(4): 421-427.
DOI: 10.61558/2993-074X.1403
Available at: https://jelectrochem.xmu.edu.cn/journal/vol6/iss4/5

References

[1]　LiWen jie .Theapplicationofsuperoxidedismutaseintheaging resistanceandtheremedyofdiseaseinducedbysuperoxideradical[J].J .ChinesePharmaceutic(Chinese) .1989,2 4 ( 7) :397.(李文杰 .超氧化物歧化酶在治疗超氧阴离子自由基所引起的疾病及抗衰老上的应用 [J].中国药学杂志 ,1989,2 4 ( 7) :397 4 0 1)

[2 ]　NiXing Zhong .Clinicalbiochemicalenzymereagentmethod[M ].EastofChinaNormalUniversity(Chi nese) ,1993.(倪星忠 ,临床生化酶试剂方法 [M].华东师范大学出版社 ,1993:113)

[3]　YuanQin Sheng .Theaspectsandprospectiveofsuperoxidedismutase[J].J.ChinesePharmaceutic(Chi nese) .1991,2 6( 8) 456 4 59(袁勤生 .超氧化物歧化酶的研究现状及应用前景 [J].中国药学杂志 ,1991,2 6( 8) 456 4 59)

[4 ]　HanJi Lin ,ChenHiong Yuan ,QianWen ,etal.InvestigationonelectrochemicalbehaviorofCu Znsuperox ideDismutase[J].ChemicalJ.ChineseUniv .,(Chinese) .(朝吉林、陈洪渊、钱雯等 ,天然铜 锌超氧化物歧化酶的电化学行为研究 [J].高等学校化学学报 ,1994 ,15( 12 ) :1778)

[5]　RaiN .lyer ,WilliamE .Schmidt.Observationonthedirectelectrochemistryofbovinecopper zincsuperoxidedismutase[J].BioelectrochemistryandBioenergetics ,1992 ,2 7:393 4 0 4

[6]　WuXiaqin ,LiuQian ,ZhangZong rang ,etal.Electrochemicalbehaviorofsuperoxidedisumtaseongoldminigridwiththin layercell[J].Electrochemistry(chinese) ,1997,3( 2 ) :136(吴霞琴 ,刘倩、许兵 ,章宗穰[J].SOD在金微网栅电极上的电化学行为 [J].电化学 ,1997,3( 2 ) :136 138)

[7]　HuJie Han ,ShuZhan Yong .TheintrationsofCu Znsuperoxidedismutaseandhistidine[J].ScienceinChi na(SerisB) (Chinese) ,1993,2 3( 8) :793 797.(胡皆汉 ,舒占永 .铜锌超氧化物歧化酶活性中心铜与组氨酸的相互作用 [J].中国科学 (B辑 ) ,1993,2 3( 8) :793 797) .

[8]　WangJin Dui,ZhaoYing ,ShuXin .CorrelationofSODwithLDHingastricjuiceandtheirrelationshipwithmembranesystem[J].1992 ,( 3) :95 98(Chinese) .(王今堆 ,赵荧 ,苏昕等 .胃液中超氧化物歧化酶与乳酸脱氢酶的相关性及其与膜系的关系 [J].吉林大学自然科学学报 ,1992 ,( 3) :95)

[9]　Borsari.M .,Azab .H .A .Voltammetricbehaviourofbovineerythrocytesuperoxidedismutase[J].Bioelec trochemandBioenerg ,1992 ,2 7:2 2 9～ 2 33

[10 ]　WuXia Qin ,XvBin ,ZhangZong Rangetal.Thecyclicvoltammetricbehaviorofsuperoxidedismutase[J].J.ofShanghaiTeachersUniv .(Naturalscience) (Chinese) ,1997,2 6( 4 ) :4 3～ 4 8.(吴霞琴、许兵、章宗穰等 ,超氧化物歧化酶的循环伏安行为 ,上海师范大学学报 ,1997,2 6( 4 ) :4 3)

[11]　WuXiaqin ,MengXiaoyun ,ZhangZongrang .StudyontheET processofSODatcysteine modifiedgoldeletrode .Chem .Lett.,1999,12 :12 71.

[12 ]　XiaqinWu ,XiaoynuMeng ,ZhesuWang ,ZongrangZhang .Studyondirectelectrochemicalreactionofsuper oxidedismutase[J].Biochem .andBioenerg .,1999,4 8( 1) :2 7

[13]　WuXiaqin ,MengXiaoyun ,ZhangZongrangetal.Theelectrochemicalbehaviorsofsuperoxidedisumtaseatpromoter modifiedgoldelectrode[J].Electrochemistry(Chinese) ,1999,5( 4 ) :383) (吴霞琴、孟晓云、章宗穰等 ,超氧化物歧化酶在促进剂修饰的金电极上的电化学行为 ,电化学 ,1999,5( 4 ) :383)

[14]　WuXiaqin ,WangZhesu ,MengXiaoyun ,etal.Electrochemicalquartzcrystalmicrobalancestudyonthepromotedelectrontransferprocessatgoldelectrode[J].Electrochemistry ,2 0 0 0 ,6( 2 ) :163(Chinese) .(吴霞琴、王浙苏、章宗穰等 .超氧化物歧化酶在金电极上电子传递过程的EQCM研究 ,[J].电化学 ,2 0 0 0 ,6( 2 ) :163)

[15]　JohnThornton ,KenForce .Surface EnhancedRamanspectroscopyofnucleicacidcompoundsandtheirmix tures[J].Appliedspectroscopy ,1991,4 5( 9) :152 2

[16]　WilliamH .Woodruff,KennethA .Norton .CrroresonanceRamanspectroscopyofplastocyanin ,azurin ,andstellacyanin .Areevaluationoftheidentityoftheresonance enhancedmodes[J].J .Am .Chem .Soc.1983,10 5:657

[17]　H .Takeuchi,Y .Kimura ,I.koitabashi,etal.RamanbandofN deuteratedhistidiniumasmarkersofcon formationandhydrogenbonding[J].J.Ramanspectroscopy ,1991,2 2 :2 33