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Abstract

Lithium_ion batteries are well adapted to the new multimedia applications. PP/PE based microporous film is commonly used as separator in commercial lithium ion batteries. Here we report a microporous film which is superior to the commercial available separator. The microporous PVDF polymer separators were prepared by the phase inversion process. The pore size of the separator is  7 μm, and it's porosity is 75%. The membrane in LiPF 6 EC/DEC showed high ionic conductivity (above 10 -3 S/cm at room temperature), and good mechanical properties (10 3 kg/cm 2). The half_cells consisted of Li/PVDF separator/MCMB showed excellent cycling characteristics and the stable discharge capacity is 302 mAh/g.

Keywords

Separator, Lithium ion battery, PVDF, Phase inverse

Publication Date

2001-05-28

Online Available Date

2001-05-28

Revised Date

2001-05-28

Received Date

2001-05-28

References

[1] KestingRE .SyntheticPolymericMembranes .SecondEdition[M].NewYork :JohnWileyandSons,1985.

[2 ] GuH ,HuangXJ ,ChengLQ ,etal.Preparationofseparatorforlighium_ionbattery[P].ChinaPatent :0 0 10 72 4 3.9.

[3] FongR ,SackenU ,DahnJR .Studiesoflithiuminterclationintocarbonsusingnon_aqueouselectrochemicalcells[J].J .Electrochem .Soc .,1990 ,137:2 0 0 9

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