Abstract
The periodic,aperiodic,chaotic and mixed_mode oscillations can occur in the process of the anodic electrodissolution of carbon steel in the solution of dilute phosphoric acid. More plentiful dynamic behaviors can be found in this system compared with the system of Fe/H 3PO 4/Pt.
Keywords
Carbon steel, Phosphoric acid, Anodic electrodissolution, Current oscillation
Publication Date
2001-08-28
Online Available Date
2001-08-28
Revised Date
2001-08-28
Received Date
2001-08-28
Recommended Citation
Shao-yuan SHI, Jin-ping WU, Jing LIU, An LIN.
Current Oscillations in the System of Carbon Steel/Phosphoric Acid/Platinum[J]. Journal of Electrochemistry,
2001
,
7(3): Article 12.
DOI: 10.61558/2993-074X.3260
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol7/iss3/12
References
[1] PhilipRussell,JohnNewman.Currentoscillationobservedwithinthelimitingcurrentplateauforironinsulfu ricacid[J].J.Electrochem.Soc.,1986,10:2093～2096.
[2] ChaoWang,ShenhaoChen,XilingYu.Thenatureofthepotentiostaticcurrentoscillationatiron/sulfuricacidsolutioninterfaces[J].Electrochem.Acta.,1994,39(4):577～580.
[3] BassettMR ,HudsonJL .Thedynamicoftheelectrodissolutionofcopper[J].Chem.Eng.Comm.,1987,60:145～159.
[4] PunitParmananda,HowardD .Dewald,R .W .Rollins.Mixed_modeoscillationsintheelectrodissolutionofcop perinaceticacid/acetatebuffer[J].Electrochem.Acta.,1999,39(7):917～920.
[5] LevO ,WolffbergA ,PismenLM ,SheintuchM .Thestructureofcomplexbehaviorinanodicnickeldissolu tion[J].J.Chem.Phys.,1989,93:1661～1666.
[6] WeihongLi,XueliWang,KenNobe.ElectrodissolutionkineticsofironinchloridesolutionsⅦ.Experimen talpotential/currentoscillations[J].J .Electrochem.Soc.,1990,137(4):1184～1188.
[7] BourceanuG ,MelnigV ,vatamanuJ ,VasiliuR .MechanismofelectrodeoscillationsinthesystemFe/H2SO4(aq),K2Cr2O7(aq)/Pt[J].Electrochem.Acta.,1998,43(9):1031～1043.
[8] WangD ._H .,GangF ._X .,ZouJ ._Y ..Newelectrochemicaloscillationsinducedbytheabsorption_desorptionoforganiccorrosioninhibitoronFeinH2SO4 solution[J].Electrochem.Acta.,1998,43(14_15):2241～2244.
[9] NakabayashiS ,ZamaK ,UosakiK .Nonlinearironelectrochemicaloscillator:couplingandphotoeffect[J].J .Electrochem.Soc.,1991,143(7):2258～2261.
[10] GeraldoAB ,BarciaOE ,MattosOR ,HuetF ,TribolletB .Newresultsconcerningtheoscillationobservedfortheiron_sulfuricacid[J].Electrochem.Acta.,1998,44:455～465.
[11] WangChao,ChenShenhao.Holographicmicrophotographystudyoftheanodicprocessofironinsulfuricacidsolutioninamagneticfield[J].CorrosionScienceandProtectionTechnology,1999,11(1):13～23.
[12] A .J .Pearlstin,J .A .Johnson.Globalandconditionalstabilityofthestateand periodicsolutionsoftheFranck_FitzhughmodelofelectrodissolutionofFeinH2SO4[J].J .Electrochem.Soc.,1989,136:1290～1298.
[13] PhilipRussell,JohnNewman.AnodicdissolutionofironacidicsulfateelectrolytesⅡ.Mathematicalmodelofcurrentoscillationsobservedunderpotentiostaticconditions[J].J .Electrochem.Soc.,1987,5:1051～1058.
[14] HDegn.Theoryofelectrochemicaloscillations[J].Trans.FaradaySoc.,1968,64:1348～1352.
[15] DimitraSazou.Currentoscillationsandmass_transportcontrolduringelectrodissolutionofironphosphoricacidsolutions[J].Electrochem.Acta.,1997,42(4):627～637.
[16] DimitraSazou,MichaelPagitsas.Bifurcationtolimitcycleoscillationinducedbytheohmicpotentialdropduringtheanodicpolarisationofironin14.8mH3PO4[J].J .Electroanal.Chem.,451(1998):77～87.
[17] LouW ,OguraK .Currentoscillationobservedonastainlesssteelelectrodeinsulfuricacidsolutionswithandwithoutchromicacid[J].Electrochem.Acta.,1995,40(6):667～672.
[18] MRBassett,JLHudson.Shil’nikovchaosduringcopperelectrodissolution[J].J .Phys.Chem.,1988,92:6963～6966
Included in
Engineering Science and Materials Commons, Materials Chemistry Commons, Materials Science and Engineering Commons, Physical Chemistry Commons, Power and Energy Commons
