Abstract
The proton exchange membrane fuel cells(PEMFC) use proton exchange membranes(PEM) as their electrolytes. The performance of the PEMFC is strongly dependent on the characteristics of the PEM. In this paper, the requirements of the PEM utilized in the PEMFC were analyzed. The per_fluorinated, partially fluorinated and non_fluorinated PEM were introduced respectively. The structures, preparation, properties of the various types of PEM and their applications in the PEMFC were also discussed in detail.
Keywords
Proton exchange membrane fuel cells, Proton exchange membranes, Membrane structure, Cell performance
Publication Date
2001-11-28
Online Available Date
2001-11-28
Revised Date
2001-11-28
Received Date
2001-11-28
Recommended Citation
Jing-rong YU, Dan-min XING, Fu-qiang LIU, Jian-guo LIU, Bao-lian YI.
Research Progress on Proton Exchange Membranes of Fuel Cells[J]. Journal of Electrochemistry,
2001
,
7(4): 385-395.
DOI: 10.61558/2993-074X.1433
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol7/iss4/1
References
[1] YiBL .Statusandfutureoffuelcell[J].ChineseJournalofPowerSources,1998,22(5):216～221.
[2] CaiNS .Theapplicationofproton_exchangemembraneinfuelcells[J].MembraneSicenceandTechnology(Chinese),1996,16(4):1～6.
[3] SrinivasanS .Fuelcellsforextraterrestrialandterrestrialapplications[J].J .Electrochem.Soc.,1989,136:41C～48C .
[4] ApplebyAJ .Recentdevelopmentandapplicationsofthepolymerfuelcell[J].Phil.Trans.R .Soc.Land.A ,1996,354:1681～1693.
[5] RalphTR .Clearfuelcellenergyfortoday[J].PlatinumMetalRev.,1999,43(1):14～17.
[6] RalphTR .Protonexchangemembranefuelcells[J].PlatinumMetalRev.,1997,41(3):102～113.
[7] PraterKB .Therenaissanceofthesolidpolymerfuelcell[J].J.PowerSources,1990,29:239～250.
[8] HuangZ ,etal.TheResearchandApplicationsofProtonExchangeMembraneFuelCells[M ].Beijing:Pub lishingCompanyofMetallurgicalIndustry,2000.
[9] WakizoeM ,VelevOA ,SrinivasanS .Analysisofprotonexchangemembranefuelcellperformancewithal ternatemembranes[J].ElectrochimicaActa,1995,40(3):335～344.
[10] YoshitakeM ,TamuraM ,YoshidaN ,etal.Studiesofperfluorinatedionexchangemembranesforpolymerelecrtolytefuelcells[J].DenkiKagaku,1996,64(6):727～736.
[11] YoshidaN ,IshisakiT ,WatanabeA ,etal.CharacterizationofFlemionmembranesforPEFC[J].ElectrochimicaActa,1998,43(24):3749～3754.
[12] SavadogoO .Emergingmembranesforelectrochemicalsysytems:(I)solidpolymerelectrolytemembranesforfuelcellsyytems[J].J .NewMat.forElectrochem.Systems,1998,1:47～66.
[13] LoNostroP ,ChoiS_M ,KuC_Y ,etal.FluorinatedMicroemulsions:Astudyofthephasebehaviorandstructure[J].J.Phys,Chem.B ,1999,103:5347～5352.
[14] KomoroskiRA ,MauritzKA .Asodium_23nuclearmagneticresonancestudyofionicmobilityandcontactionpairinginaperfluorosulfonateionomer[J].J.Am.Chem.Sco.,1978,100:7487～7489.
[15] HsuWY ,GirerkeTD .IontransportandclusteringinNafionperfluorinatedmembranes.[J].J.MembranceSci.,1983,13:307～326.
[16] LeePC ,MeiselD .Luminescencequenchingintheclusternetworkofperfluorosulfonatemembrane[J].J .Am.Chem.Soc.,1980,102:5477～5481.
[17] PourcellyG ,OikonomouA ,GavachC .Influenceofthewatercontentonthekineticsofcounter_inotrans portinperfluorosulphonicmembranes[J].J.Electroanal.Chem.,1990,287:43～59.
[18] Jr.ZawodzinskiTA ,DerouinC ,RadziskiS ,etal.WateruptakebytransportthroughNafion117membrane[J].J.Electrochem.Soc.,1993,140:1041～1047.
[19] Jr.ZawodzinskiTA ,SpringerTE ,DaveyJ,etal.Acomparativestudyofwateruptakebyandtransportthroughionomericfuelcellmembrance[J].J .Electrochem.Soc.,1993,140:1981～1985.
[20] Jr.ZawodzinskiTA ,NeemanM ,SillerudLO ,etal.Determinationofwaterdiffusioncoefficientsinperflu orosulfonateionomericmembranes[J].J.Phys.Chem.,1991,95:6040～6044.
[21] PennerRM ,MartinCR .Iontransportingcompositemembranes[J].J .Electrochem.Soc.,1985,132:514～515.
[22] LiuC ,MartinCR .Iontransportingcompositemembrances[J].J.Electrochem.Soc.,1990,137:510～515.
[23] VerbruggeMW ,HillRF ,SchneiderEW .Compositemembranesforfuel_cellapplications[J].AICHEJournal,1992,38(1)93～100.
[24] TaziB ,SavadogoO .ParametersofPEMfuel_cellsbasedonnewmembranesfabricatedfromNafion,silico tungsticacidandthiophene[J].ElectrochimicaActa,2000,45(24):4329～4339.
[25] SavinellR ,YeagerE ,TrykD ,etal.Apolymerelectrolyteforoperationattemperaturesupto200℃[J].J .Electrochem.Soc.,1994,141:L46～L48.
[26] MalhotraSandDattaR .Membrane_supportednonvolatileacidicelectrolytesallowhighertemperatureopera tionofprotonexchangemembranefuelcells[J].J .Electrochem.Soc.,1997,144:L23～L26.
[27] AntonucciPL ,AricoAS ,CretiP ,etal.Investigationofadirectmethanolfuelcellbasedonacompositenafion_silicaelectrolyteforhightemperatureoperation[J].SolidStateIonics,1999,125:431～437.
[28] DoyleM ,ChoiSK ,ProulxG .High_temperatureprotonconductingmembranesbasedonperfluorinatedionomormembrane_ionicliquidcomposites[J].J .Electrochem.Soc.,2000,147:34～37.
[29] WeiJ ,StoneC ,SteckAE .Trifluorostyreneandsubstitutedtrifluorostyrenecoplymericcompositionsandion_exchangemembranesformedtherefrom[P].U .S .Patent,5422411,1995_6_6.
[30] BasuraVI ,BeattiePD ,HoldcroftS .Solid_stateelectrochemicaloxygenreductionatPt|Nafion117andPt|BAM 3GTM407interfaces[J].J .Electroanal.Chem.,1998,458:1～5.
[31] BasuraVI,BeattiePD ,HoldcroftS .TemperatureandpressuredependenceofO2 reductionatPt|Nafion117andPt|BAMTM407interfaces[J].J.Electroanal.Chem.,1999,468:180～192
[32] AgostinoD ,LeeJY ,Jr.CookEH .Trifluorostyrenesulfonicacidmembranes[P].U .S .Patent,4012303,1977_3_15.
[33] TakshiM ,KozuoT ,HiroshiM ,etal.Methodforpreparationofgraftpolymericmembranes[P].U .S .Patent,4605685,1986_8_12.
[34] NezuS ,GondoM .Solid_polymer_electrolytemembranesforfuelcellandprocessforproducingthesame[P].U .S .Patent,5994426,1999_11_30.
[35] WangH ,CapuanoGA .Behaviourofraiporeradiation_graftedpolymermembrnesinH2/O2 fuelcells.[J].J .Electrochem.Soc.,1998,145:780～784.
[36] GuptaB ,BuchiFN ,SchererGG .Cationexchangemembranesbypre_irradiationgraftingofstyreneintoFEPfilms.Ⅰ.Influenceofsynthesisconditions[J].J.AppliedPolymerScience:PartA :PolymerChem istry,1994,32:1931～1938.
[37] GuptaB ,BuchiFN ,StaubM ,etal.Cationexchangemembranesbypre_irradiationgraftingofstyreneintoFEPfilms.Ⅱ.Propertiesofcopolymer[J].J.AppliedPolymerScience:PartA :PolymerChemistry,1996,34:1873～1880.
[38] LehtinenT ,SundholmG ,HolmbergS ,etal.ElectrochemicalcharacterizationofPVDF_basedprotoncon ductingmembranesforfuelcells[J].ElectrochimicaActa,1998,43(12-13):1881～1890.
[39] RouillyMV ,KotzER ,HaasO ,etal.ProtonexchangemembranespreparedbysimultaneousradiationgraftingofstyreneontoTeflon_FEPfilms.Synthesisandcharacterization[J].J .MembraneScience,1983,81:89～95.
[40] BuchiFN ,GuptaB ,HaasO ,etal.Performanceofdifferentlycross_linked,partiallyfluorinatedprotonex changemembranesinpolymerelectrolytefuelcells[J].J .Electrochem.Soc.,1995,142:3044～3048.
[41] BuchiFN ,GuptaB ,HaasO ,etal.Studyofradiation_graftedFEP_g_polystyrenemembranesaspolymerelectrolytesinfuelcells[J].ElectrochimicaActa,1995,40(3):345～353.
[42] GuoQ ,PintauroPN ,TangH ,etal.Sulfononatedandcrosslinkedpolyphosphazene_basedproton_exchangemembranes[J].J.MembraneScience,1999,154:175～181.
[43] MattssonB ,EricsonH ,TorellLM ,elal.Degradationofafuelcellmembrane,asrevealedbymicro_Ra manspectroscopy[J].ElectrochimicaActa,2000,45:1405～1408.
[44] WangJT ,WainrightJS ,SavinellRF ,etal.Adirectmethanolfuelcellusingacid_dopedpolybenzimi dazoleaspolymerelectrolyte[J].JAppliedElectrochemistry,1996,26:751～756.
[45] SavinellRF ,LittMH .Protonconductingsolidpolymerelectrolytespreparedbydirectacidcasting[P].U .S .Patent,6025085,2000_2_15.
[46] WangJT ,SavinellRF ,WainrightJS ,etal.AH2/O2 fuelcellusingaciddopedpolybenzimidazoleaspoly merelectrolyte[J].ElectrochimicaActa,1996,41:193～197.
[47] LiQF ,HjulerHA ,BjerrumNJ .Polymerelectrolytemembranesforadvancedfuelcellsusingimpurehy drogen,intheproceedingofthe13th worldhydrogenenergyconference[J].Beijing,China,2000:723～728.
[48] LiQF ,HjulerHA ,BjerrumNJ .Oxygenreductiononcarbonsupportedplatinumcatalystsinhightemper aturepolymerelectrolytes[J].ElectrochimicaActa,2000,45:4219～4226.
[49] XingB ,SavadogoO .Theeffectofaciddopingontheconductivityofpolybenzimidazole(PBI)[J].J .NewMat.forElectrochem.Systems,1999,2:95～101.
[50] InzeltG ,PineriM ,SchultzeJW ,etal.Electronandprotonconductingpolymers:recentdevelopmentsanprospects[J].ElectrochimicaActa,2000,45:2403～2421.
[51] DrzewinskiM ,MacknightWJ .Structureandpropertiesofsulfonatedpolysulfoneionomers[J].J.AppliedPolymerScience,1985,30:4753～4770.
[52] LinkousCA ,AndersonHR ,KopitzkeRW ,etal.Developmentofnewprotonexchangemembraneelec trolytesforwaterelectrolysisathighertemperatures[J].J.HydrogenEnergy,1998,23:525～529.
[53] NolteR ,LedjeffK ,BauerM ,etal.Partiallysulfonatedpoly(aryleneethersulfone)_Aversatileprotoncon ductingmembranematerialformodenenergyconversiontechnologies[J].J .MembraneScience,1993,83:211～220.
[54] KobayashiT ,RikukawaM ,SanuiK ,etalProton_conductingpolymersderivedfrompoly(ether_etherke tone)andpoly(4_phenoxybenzoy1_1,4_phenylene)[J].SolidStateIonics,1998,106:219～225.
[55] BaradieB ,PoinsignonC ,SanchezJY ,etal.ThermostableionomericfilledmembraneforH2/O2 fuelcell[J].J.PowerSources,1998,74:8～16.
[56] ParkMW ,YangJC ,HanHS ,etal.HeterpolyacidincorporatedsolidpolymerelectrolyteforPEMFC[J].DENKIKAGAKU ,1996,64(6):743～748.
[57] ZaidiSMJ,MikhailenkoSD ,GuiverMD ,etal.Protonconductingcompositemembranesfrompolyetheretherketoneandheterpolyacidsforfuelcellapplications[J].J .MembraneScience,2000,173:17～34.
[58] EhrenbergSG ,SerpicoJM ,WnekGE ,etal.Fuellcellincorporationgnovelion_conductingmembrane[P].U .S .Patent,5468574,1995_11_21
Included in
Catalysis and Reaction Engineering Commons, Engineering Science and Materials Commons, Materials Chemistry Commons, Materials Science and Engineering Commons, Physical Chemistry Commons, Power and Energy Commons
