Abstract
A new electroactive poly(2,2' diaminophenyloxydisulfide) (PDAPD) was successfully synthesized from acetonitrile(AN)/tetrahydrofuran(THF)solutions containing the supporting electrolyte(LiClO 4)and the various kinds of acids(HCl,CF 3COOH,CCl 3COOH) on Pt electrode by consecutive cyclic voltammiry. The effects of the concentrations of supporting electrolyte(LiClO 4) and acid(HCl,CF 3COOH,CCl 3COOH) on electrodepositon of PDAPD film were investigated. The best experimental conditions for electrosynthesis of a highly electroactive conducting polymer film are that the concentrations are 0.1 mol/L and between 0.05 mol/L～0.5 mol/L,respectively for LiClO 4 and HCl.
Keywords
Poly(2, 2' diaminophenyloxydisulfide), Electrosynthesis, Conducting polymer, Electroactivity
Publication Date
2001-11-28
Online Available Date
2001-11-28
Revised Date
2001-11-28
Received Date
2001-11-28
Recommended Citation
Yu zhi SU, Yan wen RAO, Ye YANG, Mei-bing CHEN, Yin ling QIU, Yong-hua ZHANG, Ke cheng GONG.
Electrosynthesis of A New Electroactive Poly(2,2'-Diaminophenyloxydisulfide)[J]. Journal of Electrochemistry,
2001
,
7(4): 465-471.
DOI: 10.61558/2993-074X.1440
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol7/iss4/8
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