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Corresponding Author

Zu_geng LIN

Abstract

In the present work, Ni0.67Mg0.33O and NiO were produced by sol_gel method, and characterized by XRD, a rietveld refinement and the discharge/charge test.It was found that the magnesium_doping restrained the reduction of Ni and decreased the reversible capacity for the sample of Ni0.67Mg0.33O. But the formation of the solid solution after the magnesium_doping facilitated the high dispersion of NiO, and accordingly improved the electrochemical performance.

Publication Date

2003-02-28

Online Available Date

2003-02-28

Revised Date

2003-02-28

Received Date

2003-02-28

References

[1] PolzetP,LaruellS,GrugeonS,etal.Nano-sizedtransition-metaloxidesasnegative-electrodemateri-alsforlithium-ionbatteries[J].Nature,2000,407:496~499.

[2] NakayamaT,IchikuniN,SatoS,etal.Ni/MgOcatalystprepatedusingcitricacideforhydrogenationofcarbondioxide[J].Appl.Catal.A,1997,158:185~199.

[3] YoungRA,SakthivelA,MossTS,etal.DBWS-9411-anupgradeoftheDBWS*.*programsforri-etveldrefinementwithPCandmainframecomputers[J].J.Appl.Cryst.,1995,28:366~367

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