•  
  •  
 

Corresponding Author

Hu_lin LI

Abstract

A novel alkylthiol molecule containing ferrocene and pyridium moieties and its hydrogenated products were synthesized and subsequently assembled on Au electrode as SAMs. Cyclic voltammogram(CV) was used to investigate the structure_dependent electrochemical response of the SAMs in 0.1 mol/L HClO4 aqueous solution.

Publication Date

2003-05-28

Online Available Date

2003-05-28

Revised Date

2003-05-28

Received Date

2003-05-28

References

[1] UlmanA.AnIntroductiontoUltrathinOrganicFilms:FromLangmuir_BlodgetttoSelf_assembly[M].SanDiego,CA:AcademicPress,1999.

[2] KondoT,HoriuchiS,YagiI,etal.Electrochemicalcontrolofthesecondharmonicgenerationpropertyofself_assembledmonolayerscontainingatrans_ferrocenyl_nitrophenylethylenegroupongold[J].J.Am.Chem.Soc.1999,121(2):391~398.

[3] SumnerJJ,WeberKS,HockettLA,etal.Long_rangeheterogeneouselectrontransferbetweenferroceneandgoldmediatedbyn_alkaneandn_alkyl_carboxamidebridges[J].J.Phys.Chem.B.2000,104(31):7449~7454.

[4] SumnerJJ,CreagerSE.Topologicaleffectsinbridge_mediatedelectrontransferbetweenredoxmoleculesandmetalelectrodes[J].J.Am.Chem.Soc.2000,122(48):11914~11920.

[5] KondoT,KanaiT,UosakiK.Controlofthecharge_transferrateatagoldelectrodemodifiedwithaself_assembledmonolayercontainingferroceneandazobenzenebyelectro_andphotochemicalstructuralconversionofcisandtransformsoftheazobenzenemoiety[J].Langmuir.2001,17(20):6317~6324.

[6] NapperAM,LiuHY,WaldeckDH.Thenatureofelectroniccouplingbetweenferroceneandgoldthroughalkanethiolatemonolayersonelectrodes:impotranceofchaincomposition,Interchaincouplingandquantuminterface[J].J.Phys.Chem.B.2001,105:7699~7707.

[7] SumnerJJ,CreagerSE.Redoxkineticsinmonolayersonelectrodes:Electrontransferissluggishforferrocenegroupsburiedwithinthemonolayerinterior[J].J.Phys.Chem.B.2001,105(37):8739~8745.

[8] ZhangXG,ShiYL,LiHL.Theeffectofwatercontentinacetonitrileontheelectrochemistryofferrocenylthiolself_assembledmonolayers[J].ColloidandInterfaceScience.2001,246:296.

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.