Ordered porous titanium phosphate materials were prepared by using the surfactant template combined with the sol-gel method.The samples were characterized by small angle X-ray diffraction(SA-XRD) method,N2 adsorption/desorption techniques,high resolution transmission electron microscopy(HRTEM) and element analysis.It is found that the calcination temperature is a big influence on the porous structure,and electrochemical performance of the titanium phosphate materials.,and the mesoporous titanium phosphate showed good performance in the electrochemical test,the first discharge capacity is 94 mAh/g at the current density of 150 mA/g.On the other hand,the no porous material with a low capacity of 37 mAh/g under the same charge-discharge condition.


ordered mesoporous, titanium phosphate, cathode material, electrochemical performance, lithium ion battery

Publication Date


Online Available Date


Revised Date


Received Date



[1]Chung S Y,Bloking J T,Chiang Y M.Electronicallyconductive phospho-olivines as lithium storage elec-trodes[J].Nature Materials,2002.1:123.
[2]SHI Zhi-cong(施志聪),LI Chen(李晨),YANG Yong(杨勇).Study on electrochemical performance of anew type cathode material of LiFePO4[J].Electro-chemistry(in Chinese),2003,9(1):9.
[3]Tarascon J M,Armand M.Issues and challenges facingrechargeable lithium batteries[J].Nature,2001,414:359.
[4]Kavan L,Kalbac M,Zukalova M,et al.Lithium storagein nanostructured TiO2made by hydrothermal growth[J].Chem Mater,2004,16:477.
[5]Gao X,Zhu H,Pan G,et al.Preparation and electro-chemical characterization of anatase nanorods for lithi-um-inserting electrode material[J].Phys Chem B,2004,108:2868.
[6]Shi Z C,Wang Q,Ye W L,et al.Synthesis and char-acterization of mesoporous titanium pyrophosphate aslithium intercalation electrode materials[J].Micro-porous and Mesoporous Materials,2006,88(1~3):232-237.
[7]Shi Z C,Li Y X,Ye W L,et al.Mesoporous FePO4with enhanced electrochemical performance as cathodematerials of rechargeable lithium batteries[J].Electro-chemical and Solid State Letters,2005,8(8):A396-A399.
[8]Huo Q,Margolese D I,Stucky G D.Surfactant controlof phases in the synthesis of mesoporous silica-basedmaterials[J].Chem Mater,1996,8:1147.
[9]Huo Q,Margolese D I,Ciesia Feng,et al.Genealizedsynthesis of periodic surface/inorganic composite mate-rials[J].Nature,1994,368(6469):317.
[10]Kresge C T,Leonowicz ME,Roth W J,et al.Orderedmesoporous molecular sieves synthesized by a liquid-crystal template mechanism[J].Nature,1992,359(6397):710.
[11]Beck J S,Vartuli J C,Roth W J,et al.A new familyof mesoporous molecular sieves prepared with liquidcrystal templates[J].J Am Chem Soc,1992,114:10834.
[12]Huo Q,Leon R,Petroff P M,et al.Mesostructure de-sign with gemini surfactants:Supercage formation in athree-dimensional hexagonal array[J].Science,1995,268(5215):1324.
[13]Yang P D,Zhao D Y,David I Margolese,et al.Gen-eralized syntheses of large-poremesoporous metal oxideswith semi-crystalline frameworks[J].Nature,1998,396(6707):152-155.
[14]XU Ru-ren(徐如人),PANG Wen-qin(庞文琴),YUJi-hong(于吉红),et al.Sieve and porous materialschemistry[M].Beijing:Science Publishing Company,2004.
[15]Sébastien Patoux,Christian Masquelier.Lithium inser-tion into titanium phosphates,silicates,and sulfates[J].Chem Mater,2002,14:5057-5068.



To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.