Preparation and Electrochemical Properties of Layered Manganese Oxide(Li-birnessite Type)

Authors

Xing-kang HUANG, Fujian Nanping Nanfu Battery Company Limited,Nanping 353000,Fujian,China;State Key Laboratory for Physical Chemistry of Solid Surfaces,Department of Chemistry,Xiamen University,Xiamen 361005,Fujian,China;
Hai-tao CHANG, Fujian Nanping Nanfu Battery Company Limited,Nanping 353000,Fujian,China;
Jian-long GAN, Fujian Nanping Nanfu Battery Company Limited,Nanping 353000,Fujian,China;
Qing-shun ZHANG, Fujian Nanping Nanfu Battery Company Limited,Nanping 353000,Fujian,China;
Hong-jun YUE, State Key Laboratory for Physical Chemistry of Solid Surfaces,Department of Chemistry,Xiamen University,Xiamen 361005,Fujian,China;
Dong-ping LV, State Key Laboratory for Physical Chemistry of Solid Surfaces,Department of Chemistry,Xiamen University,Xiamen 361005,Fujian,China;
Yong YANG, State Key Laboratory for Physical Chemistry of Solid Surfaces,Department of Chemistry,Xiamen University,Xiamen 361005,Fujian,China;Follow

Corresponding Author

Yong YANG(yyang@xmu.edu.cn)

Abstract

Layered Li-birnessite was prepared by means of oxidizing Mn²⁺ with O₂ gas in alkaline media.The as-prepared sample was characterized by scanning electron microscopy(SEM), X-ray diffraction(XRD), BET and thermogravimetric/diffenential thermal analysis(TG/DTA) techniques. The electrochemical properties of the material were also investigated. The results show that such a Li-birnessite consists of well-crystallized spherical particles with an interlayer distance of 0.70 nm. The Li-birnessite delivered a high discharge capacity of 203 mAh/g at a rate of 0.2 C(40 mA/g), and had good rate capability as well.

Keywords

layered manganese oxide, Li-birnessite, rechargeable lithium batteries, electrochemical properties

DOI Link

https://doi.org/10.61558/2993-074X.1978

Publication Date

2009-05-28

Online Available Date

2009-05-28

Revised Date

2008-12-19

Received Date

2008-10-11

Recommended Citation

Xing-kang HUANG, Hai-tao CHANG, Jian-long GAN, Qing-shun ZHANG, Hong-jun YUE, Dong-ping LV, Yong YANG. Preparation and Electrochemical Properties of Layered Manganese Oxide(Li-birnessite Type)[J]. Journal of Electrochemistry, 2009 , 15(2): 194-197.
DOI: 10.61558/2993-074X.1978
Available at: https://jelectrochem.xmu.edu.cn/journal/vol15/iss2/13