Electrochemical Behaviors of Hydrazine in BmimPF₆ Solution at Ag Electrode

Authors

Jie SUN, College of Life and Environment Sciences,Shanghai Normal University, Shanghai 200234,China;
Yan LI, College of Life and Environment Sciences,Shanghai Normal University, Shanghai 200234,China;
Yi-ling FENG, College of Life and Environment Sciences,Shanghai Normal University, Shanghai 200234,China;
Rong WANG, College of Life and Environment Sciences,Shanghai Normal University, Shanghai 200234,China;Follow
Xia-qin WU, College of Life and Environment Sciences,Shanghai Normal University, Shanghai 200234,China;

Corresponding Author

Rong WANG(wangrong@shnu.edu.cn)

Abstract

In this work,the electrochemical behaviors of hydrazine at Ag electrode in the room temperature ionic liquid,BmimPF₆,were studied by cyclic voltammetry. Results suggested that Ag electrode showed a good catalytic activity towards hydrazine oxidation. The catalytic peak current showed a good linear relationship with the hydrazine concentration in the range of 0 ～ 3. 4 mmol/L. The rate-determining step of the electrocatalytic reaction involved one electron transfer form hydrazine molecule to Ag⁺ ion.

Keywords

ionic liquid, hydrazine, electrocatalytsis, BmimPF6

DOI Link

https://doi.org/10.61558/2993-074X.3343

Publication Date

2010-05-28

Online Available Date

2010-05-28

Revised Date

2010-01-26

Received Date

2009-12-20

Recommended Citation

Jie SUN, Yan LI, Yi-ling FENG, Rong WANG, Xia-qin WU. Electrochemical Behaviors of Hydrazine in BmimPF₆ Solution at Ag Electrode[J]. Journal of Electrochemistry, 2010 , 16(2): 198-201.
DOI: 10.61558/2993-074X.3343
Available at: https://jelectrochem.xmu.edu.cn/journal/vol16/iss2/15