Corresponding Author

Zheng LIU(lisa4.6@163.com)


The Schiff base nickel complexes/graphene oxide/glassy carbon electrodes were prepared by embedded method and electrodeposition on which were used to quantitatively detect the contents of carmine. Cyclic voltammetry, chronoamperometry, scanning electron microscopy (SEM) and other methods were employed to characterize properties and morphologies of the modified electrodes. The results show that the adamantane double Schiff base nickel complexes/graphene oxide/glassy carbon electrode had high electric catalytic activity toward carmine oxidation reaction, and might provide an easy and quick way to detect carmine content with good reproducibility.

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[1] Li W(李巍), Liu Z(刘峥), Wei X(魏席), et al. S Study on rapid detection of lemon yellow by fluorescence sensor using Isatin Double Schiff graphite oxide[J]. China Food Additives(中国食品添加剂),2014,(9):195-200.

[2] The ministry of health of the People's Republic of China. Hygglenic standards for uses of food additivves[S].BeiJing: China Standard Press(中国标准出版社), 1997.

[3] Ma Y J(马亚军), Wang R B(王瑞斌). Synthesis a new schiff base and its Cu (Ⅱ), Co (Ⅱ) and its catalytic properties[J]. chemical regent(化学试剂),2010,32(9):829-831.

[4] Zhen T(郑挺), Huang S M(黄时绵), Zhou B(周博), et al. Synthesis and α-glucosidase inhibitory activity of polyhydroxybenzaldehyde Schiff bases[J]. Chinese Journal of Medicinal Chemisstry(中国药物化学杂志),2011,20(5):370-375.

[5] Xia J B(夏江滨), Yang H, Li F Y, et al. Synthesis of a novel complex of Schiff-base and Zine and Application to Sensitized Nanocrystalline TiO2 Solar Cell[J]. Chemical Journal of Chinese Universities(高等学校化学学报), 2006,27(2):204-208.

[6] Li Y H(李玉红), Liu H X, Xu B, et al. The Culture of Tobacco Suspenion Cells and the Isolation of Organelles[J]. Journal of Capital Normal Universsity(Natural Science Edition)(首都师范大学学报(自然科学版),2007, 28(2): 54-57.

[7] Shi P, Wang B X, Song X L, et al. Application of Pd/Graphene Modified Electrode in the Detection of 4-Chlorophenol[J]. Journal of Electrochemissstry, 2015, 21(5): 488-495.

[8] Daniele M, Francessco R, Stefano P, et-al. ω-Thio nitrilotriacetic chemically modified gold electrode for iron determination in natural waters with different salinity [J]. Talanta 2014,130:90-95.

[9] Aidan F-M, Marcus C A, Bhavik A.P. Chemically modified multiwall carbon nanotube composite electrodes:An assessment of fabrication strategies [J]. Electrochimica Acta 2015,152(10):249-254.

[10] Taei M, Hasanpour F, Salavati H, et al. Simultaneous determination of cysteine, uric acid and tyrosine using Au-nanoparticles/poly(E)-4-(p-tolyldiazenyl) benzene-1,2,3-triol film modified glassy carbon electrode [J]. Materials Science and Engineering:C. 2016,59(1):120-128.

[11] Liu Z(刘峥), Zhang X G(张小鸽), Xuan S(袁帅), et al. The preparation and application in food analysis of Ni(Ⅱ) Schiff-base complex modified carbon paste electrode[J]. Food Sccience and Technology(食品科技),

[12] Wang L, Xu L. Cyclic Voltammetric Determination of Free and Total Sulfite in Muscle Foods Using an Acetylferrocene€“Carbon Black€“Poly (vinyl butyral) Modified Glassy Carbon Electrode[J]. Journal of agricultural and food chemistry, 2014, 62(42): 10248-10253.

[13] Xiaoliang Y, Yongling D, Daban L, et al. Rication of β-cyclodextrin-coated poly (diallyldimethylammonium chloride)-functionalized graphene composite film modified glassy carbon-rotating disk electrode and its application for simultaneous electrochemical determination colorants of sunset yellow and tartrazine[J].Analytica Chimica Acta 2013,779:22-34.

[14] Meiling W, Jinjiang Z Yun qiao G, et al. Determination of Sunset Yellow in Soft Drinks at Attapulgite odified Expanded Graphite Paste Electrode[J].Journal of The Electrochemical Society, 2014,161(3):86-91.

[15] Combeau S, Chatelut M, Vittori O. Identification and simultaneous determination of Azorubin, Allura red and Ponceau 4R by differential pulse polarography: application to soft drinks[J]. Talanta, 2002, 56(1): 115-122.

[16] Claux B, Vittori O. Bismuth film electrode as an alternative for mercury electrodes: Determination of azo dyes and application for detection in food stuffs[J]. Electroanalysis, 2007, 19(21): 2243-2246.

[17] Mojdeh E, Mohammad Khalilzadeh A,Hassan K. High sensitive voltammetric sensor based on Pt/CNTs nanocomposite modified ionic liquid carbon paste electrode for determination of Sudan I in food samples[J].Food Chemistry,2013,141:4311-4317.

[18] Jing Zhang,Xue Wang,Shibo Zhang et al. An Electrochemical Sensor for Simultaneous Determination of Ponce 4R and Tartrazine Based on an Ionic Liquid Modiied Expanded Graphite Paste Electrode[J]. Journal of The Electrochemical Society, 2014,161(9):H453-H457.

[19] Wenyang Wang,Ruifeng Li,Xia Hua et al. Methanol electrooxidation on glassy carbon electrode modified with bimetallic Ni(II)Co(II)salen complexes encapsulated in mesoporous zeolite A[J]. Electrochimica Acta,2015,163:48-56.

[20] Ge H , Ling B H , Sun Z R . Research progress in removing chlorinated organic compounds by electrochemical process[J]. Environmental Protection of Chemical Industry(化工环保), 2008, 28(4): 317-322.

[21] Wang L, Lv Y Q, Yang Z B, et al.Levodopa in single wall carbon nanotubes modified electrode electrochemical behavior[J]. Analysis Laboratory(分析试验室), 2006, 23(6): 13-15.

[22] Xiao J J(肖静婧), Xu H Y(徐慧颖), Xu L(徐莉), et al. Electroemical Detection of L-cyssteine Based on Iron Phthalocyanine/Nitrogen-Doped Graphene Modiffied Electrodes[J]. Journal of Electrochemissstry, 2015.21(1):53-57.

[23] Abdoulaye Thiam, Enric Brillas, Francesc Centellas, et al. Electrochemical reactivity of Ponceau 4R (food additive E124) in different electrolytes and batch cells,Electrochimica Acta, 2015, 173: 523€“533

[24]Roslonek G,Taraszewska J. Electrocatelytic oxidation of alcohols on glassycarbon electrodes electrochemically modified with nickel tetraazamacrocycliccomplexes[J]. J Electroanal Chem,1992,325:285-283.



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