Abstract
Electrohydrodimerization(EHD) of fumarodinitrile on liquid gallium electrode can take place not only in hydrotropic solution of tetraethylammonium p_toluenesulphonate(TEA_PTS), but also in aqueous solution containing low concentration of strong surfactants, such as TritonX_100. In solution without organic surfactant, FDN yields a single two_electron reduction wave corresponding to the formation of a saturated monomer called as butanedinitrile. If some TEA_PTS or TritonX_100 is added into the solution, the original two_electron wave is splitted into two continuous single_electron reduction wave and corresponding EHD of fumarodinitrile is obtained.
Keywords
Gallium, Electroreduction, Electrohydrodimerization, Polarography, Fumarodinitrile
Publication Date
1999-02-28
Online Available Date
1999-02-28
Revised Date
1999-02-28
Received Date
1999-02-28
Recommended Citation
He Wei, Huang Ying.
Electrohydrodimerization of Fumarodinitrile on Liquid Gallium Electrode[J]. Journal of Electrochemistry,
1999
,
5(1): Article 16.
DOI: 10.61558/2993-074X.3162
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol5/iss1/16
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