Catalytic Effect of Cl~- on Electrodeposition of Binary Zinc Alloys With Iron group Metals

Authors

Ren-he YIN, Shanghai Univ., Shanghai Bao shan, 200436,China;
Zheng hua FANG, Shanghai Univ., Shanghai Bao shan, 200436,China;
Wei min CAO, Shanghai Univ., Shanghai Bao shan, 200436,China;
A.ZAKARIA A.ZAKARIA, Shanghai Univ., Shanghai Bao shan, 200436,China;
Rong-ming ZHOU, Shanghai Univ., Shanghai Bao shan, 200436,China;

Corresponding Author

Ren he YIN

Abstract

Zinc iron group metal alloys were deposited under coulostatic (10C.cm -2 ) at 40 ℃ chloride baths. The deposited alloys were quantitatively analyzed by Atomic Absorption Spectrometry. The current efficiency, percent content and partial polarization curves were obtained by the results. The morphology of the deposits was observed by means of Scanning Electron Microscopy(SEM). We observe that the electrodeposition of zinc iron group metal alloys is one of the best known examples of anomalous codeposition. We found the catalytic effect of Cl - on the electrodeposition behavior of iron group metal. Overpotential of iron group metal droped abruptly at high Cl - concentration, while transition current density of Zn increased gradually.

DOI Link

https://doi.org/10.61558/2993-074X.3243

Publication Date

2001-02-28

Online Available Date

2001-02-28

Revised Date

2001-02-28

Received Date

2001-02-28

Recommended Citation

Ren-he YIN, Zheng hua FANG, Wei min CAO, A.ZAKARIA A.ZAKARIA, Rong-ming ZHOU. Catalytic Effect of Cl~- on Electrodeposition of Binary Zinc Alloys With Iron group Metals[J]. Journal of Electrochemistry, 2001 , 7(1): Article 23.
DOI: 10.61558/2993-074X.3243
Available at: https://jelectrochem.xmu.edu.cn/journal/vol7/iss1/23

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