Authors
Ao Du, Tianjin Key Laboratory of Advanced Carbon and Electrochemical Energy Storage, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, P. R. China.
Juan Zhang, CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences (CAS), Beijing 100190, P. R. China.
Pan Xu, Beijing Key Laboratory of Complex Solid-State Batteries & Tsinghua Center for Green Chemical Engineering Electrification, Department of Chemical Engineering, Tsinghua University, Beijing 100084, P.R. China.
Ya-Jie Li, State Key Laboratory of Materials for Advanced Nuclear Energy & School of Materials Science and Engineering, Shanghai University, Shanghai 200444, P. R. China.
Kang-Yu Yi, State Key Laboratory of Precision and Intelligent Chemistry, University of Science and Technology of China, Hefei, 230026, P. R. China.
Zhen-Zhen Shen, CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences (CAS), Beijing 100190, P. R. China; State Key Laboratory of Chemical Resource Engineering, Beijing Key Laboratory of Electrochemical Process and Technology of Materials, Beijing University of Chemical Technology, Beijing 100029, P. R. China.
Hui-Lin Ge, Tianjin Key Laboratory of Advanced Carbon and Electrochemical Energy Storage, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, P. R. China.
Guang-Wen Zhang, Tianjin Key Laboratory of Advanced Carbon and Electrochemical Energy Storage, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, P. R. China.
Chao-Hui Zhang, CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences (CAS), Beijing 100190, P. R. China.
Yu-Hao Wang, CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences (CAS), Beijing 100190, P. R. China.
Chen-Zi Zhao, Beijing Key Laboratory of Complex Solid-State Batteries & Tsinghua Center for Green Chemical Engineering Electrification, Department of Chemical Engineering, Tsinghua University, Beijing 100084, P.R. China; The Innovation Center for Smart Solid State Batteries, Yibin 644002, P. R. China.
Meng-Yang Xu, State Key Laboratory of Materials for Advanced Nuclear Energy & School of Materials Science and Engineering, Shanghai University, Shanghai 200444, P. R. China.
Yu-Lin Jie, State Key Laboratory of Precision and Intelligent Chemistry, University of Science and Technology of China, Hefei, 230026, P. R. China.
Rui Wen, CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences (CAS), Beijing 100190, P. R. China; School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, P. R. China.Follow
Shu-Hong Jiao, State Key Laboratory of Precision and Intelligent Chemistry, University of Science and Technology of China, Hefei, 230026, P. R. China.Follow
Si-Qi Shi, State Key Laboratory of Materials for Advanced Nuclear Energy & School of Materials Science and Engineering, Shanghai University, Shanghai 200444, P. R. China; Materials Genome Institute, Shanghai University, Shanghai 200444, P. R. China.Follow
Qiang Zhang, Beijing Key Laboratory of Complex Solid-State Batteries & Tsinghua Center for Green Chemical Engineering Electrification, Department of Chemical Engineering, Tsinghua University, Beijing 100084, P.R. China; The Innovation Center for Smart Solid State Batteries, Yibin 644002, P. R. China; Institute for Carbon Neutrality, Tsinghua University, Beijing 100084, P.R. China.Follow
Chun-Peng Yang, Tianjin Key Laboratory of Advanced Carbon and Electrochemical Energy Storage, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, P. R. China.Follow
Yu-Guo Guo, CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences (CAS), Beijing 100190, P. R. China; School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, P. R. China.Follow
Corresponding Author(s)
Rui Wen(ruiwen@iccas.ac.cn);
Shu-Hong Jiao(jiaosh@ustc.edu.cn);
Si-Qi Shi(sqshi@shu.edu.cn);
Qiang Zhang(zhang-qiang@mails.tsinghua.edu.cn);
Chun-Peng Yang(cpyang@tju.edu.cn);
Yu-Guo Guo(ygguo@iccas.ac.cn)
Abstract
Lithium metal anodes, with a theoretical capacity of up to 3860 mAh·g−1, are regarded as the cornerstone for developing next-generation high-energy-density batteries. However, several key challenges hinder their practical applications, including dendrite formation, unstable solid electrolyte interphase (SEI), side reactions with electrolytes, and associated safety risks. This review systematically explores the mechanisms of lithium nucleation, growth, and stripping in both liquid and solid-state battery systems, analyzing critical theoretical concepts like heterogeneous nucleation thermodynamics, surface diffusion kinetics, space charge effects, and SEI-induced nucleation, which are crucial for understanding the genesis of dendrite growth. Additionally, the review discusses the electrochemical-mechanical coupling failures that lead to SEI degradation and the formation of dead lithium. For liquid systems, the review proposes strategies to mitigate dendrite formation and SEI instability, which include electrolyte optimization, artificial SEI design, and electrode framework design. In solid-state batteries, the review offers a granular analysis of the interface challenges associated with polymer, sulfide, and halide electrolytes and summarizes different solutions for different solid-state electrolytes. Meanwhile, the review emphasizes the importance of advanced characterization techniques and computational modeling in understanding and regulating the interface between lithium metal and electrolytes. Looking ahead, the review highlights future research directions that emphasize the integration of cross-disciplinary approaches to tackle these interconnected challenges. By addressing these issues, the path will be clear for the rapid commercialization and widespread application of lithium metal batteries, bringing us closer to realizing stable, high-energy-density batteries that can satisfy the escalating demands of modern energy storage applications across various industries.
Graphical Abstract
Keywords
lithium metal anodes, solid electrolyte interphase, lithium dendrite, liquid-electrolyte battery, solid-state battery
DOI
10.61558/2993-074X.3594
Recommended Citation
Ao Du, Juan Zhang, Pan Xu, Yajie Li, Kangyu Yi, Zhen-Zhen Shen, Huilin Ge, Guangwen Zhang, Chao-Hui Zhang, Yu-Hao Wang, Chen-Zi Zhaoc, Mengyang Xu, Yulin Jie, Rui Wen, Shuhong Jiao, Siqi Shi, Qiang Zhang, Chunpeng Yang, Yu-Guo Guo. Regulating Lithium Metal Nucleation and Growth for Dendrite Suppression: from Liquid-Electrolyte to Solid-State Batteries[J]. Journal of Electrochemistry, doi: 10.61558/2993-074X.3594.
