Abstract
The migration of Samarium(Ⅲ)across water/nitrobenzene (w/nb) interface facilitated by diantipyrylmethane (DAM) and the electrochemical behaviour affected by emulsifier OP in the nb phase have been studied by normal and convolute cyclic voltammetry. It is concluded that the formation of the complex occurs at w/nb interface and the mechanism of the samarium(Ⅲ)transfer across w/nb interface facilitated by DAM is E mechanism.
Publication Date
1998-02-28
Online Available Date
1998-02-28
Revised Date
1998-02-28
Received Date
1998-02-28
Recommended Citation
Junwei Di, Xiaoxing Xu, Ying Wu, Ruixi Fan.
The Migration of Samarium(Ⅲ)across Oil/water Interface[J]. Journal of Electrochemistry,
1998
,
4(1): Article 18.
DOI: 10.61558/2993-074X.2683
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol4/iss1/18
References
1SamceZ，HomolkaD，MarecekV．Chargetransferbetweentwoimmiscibleelectrolytesolutions．J．Electroanal．Chem．，1982，135：2652HomolkaD，HolubK，MarecekV．Facilitatediontransferacrossthewater／nitrobenzencinterface，theo－ryforsingle－scanvoltammetryappliedtoareversiblesystem．J．Electroanal．Chem．，1982，138：293KakiuchiT．Successivecomplexformationofmultivalentionswithoctaethyleneglycoldodecyletheratthenitrobenzene／waterinterface．J．Electroanal．Chem．，1993，345：1914FanR，DiJ．Studyofthevoltammetricbehaviorofjosamycinacrossthewater－nitrobenzeneinterface．J．Electroanal．Chem．，1992，324：1075kakiuchiT，SendaM．Current－potentialcurvesforfacilitatediontransferacrossoil／waterinterfacesinthepresenceofsuccessivecomplexformation．J．Electroanal．Chem．，1991，300：4316LinS，ZhaoZ，FreiserH．Potassiumiontransferprocessesacrosstheinterfaceofanimmiscibleliquidpairinthepresenceofcrownethers．J．Electroanal．Chem．，1986，210：1377CunnaneVJ，SchifrinDJ，FleischmannM，GeblewiczG，WiliamsD．Thekineticsofionictransferacrossadsorbedphospholipidlayers．J．Electroanal．Chem．，1988，243：4558KakutaniT，NishiwakiY，OsakaiT，OhkouchiT，SendaM．Voltammetricstudyoffacilitatedtransferofionsatoil／waterinterfaces．Rev．ofPolarography．，1985，31：3169戚文彬，戚志红．新分析增效试剂．杭州：杭州大学出版社，1994：1310戚文彬．表面活性剂与分析化学（上）．北京：中国计量出版社，1986：3111YoshidaZ，KiharaS．Iontransferacrossaqueous／organicsolutioninterfaceinthepresenceofsurfac－tant．Rew．ofPolarography，1988，34：3912狄俊伟，吴莹，范瑞溪．交沙霉素推动镧（Ⅲ）在水／硝基苯界面的电化学行为．分析化学，1996，24：692
Included in
Materials Chemistry Commons, Nanoscience and Nanotechnology Commons, Physical Chemistry Commons
