Abstract
The migration of Samarium(Ⅲ) across water/nitrobenzene (w/nb) interface facilitated by diantipyrylmethane (DAM) and the electrochemical behaviour affected by emulsifier OP in the nb phase have been studied by normal and convolute cyclic voltammetry. It is concluded that the formation of the complex occurs at w/nb interface and the mechanism of the samarium(Ⅲ)transfer across w/nb interface facilitated by DAM is E mechanism.
Keywords
Oil/water interface, samarium(Ⅲ), Diantipyrymethane, Emulsifier OP, Cyclic voltammetry
Publication Date
1998-02-28
Online Available Date
1998-02-28
Revised Date
1997-08-15
Received Date
1997-06-16
Recommended Citation
Jun-wei DI, Xiao-xing XU, Ying WU, Rui-xi FAN.
The Migration of Samarium(Ⅲ) across Oil/water Interface[J]. Journal of Electrochemistry,
1998
,
4(1): 101-105.
DOI: 10.61558/2993-074X.2683
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol4/iss1/18
Included in
Materials Chemistry Commons, Nanoscience and Nanotechnology Commons, Physical Chemistry Commons