•  
  •  
 

Abstract

The transport properties and the reaction mechanism of Zn~2+ in the cathode material of Zn/V_2O_5 secondary battery with aqueous medium were studied by use of intermittent titration experiments and X-Ray diffraction analysis. The relations of some kinetic parameters to the discharge depth were discussed. The results of the experiments show that the cathodic discharge reaction is an intercalation process.

Publication Date

1998-05-28

Online Available Date

1998-05-28

Revised Date

1998-05-28

Received Date

1998-05-28

References

1(a)MurphyDW,ChristanPA,DisalvoFJetal.Vanadiumoxidecathodematerialsforsecondarylithiumcels.J.Electrochem.Soc.,1979,126:497;(b)MurphyDW,ChristanPA,DisalvoFJetal.LithiumincorporationbyV6O13andrelatedvanadium(+4,+5)oxidecathodematerials.J.Electrochem.Soc.,1981,128(10):20532DesilvestroJ,HasO.Metaloxidecathodematerialsforelectrochemicalenergystorage:AReview.J.Electrochem.Soc.,1990,137(1):5c3WestK,ZachauChristiansenB,OstergardMJLetal.Vanadiumoxidesaselectrodematerialsforrechargeablelithiumcels.J.PowerSources,1987,20:1654WestK,ZachauChristiansenB,JacobsenTetal.V6O13ascathodematerialforlithiumcels.J.PowerSources,1985,14:2355PyunSI,BaeJS.TheacimpedancestudyofelectrochemicallithiumintercalationintoporousvanadiumOxideelectrode.Electrochim.Acta,1996,41(6):9196TranchantA,BlenginoJM,FarcyJetal.Studyofthelithiumintercalation/deintercalationprocesesintoV2O5bylinearvoltammetryatslowsweeprates.J.Electrochem.Soc.,1992,139(5):12437ScarminioJ,TaledoA,AAndersonAetal.StresandelectrochromisminducedbyLiinsertionincrystalineandamorphousV2O5thinfilmelectrodes.Electrochim.Acta,1993,38(12):16378PartHK,SmyrlWH.V2O5xerogelfilmsasintercalationhostsforlithium.J.Electrochem.Soc.,1994,141(3):L259WestK,ZachauChristiansenB,JacobsenTetal.Vanadiumoxidexerogelsaselectrodesforlithiumbateries.Electrochim.Acta,1993,38(9):121510MachidaN,FuchidaR,MinamiT.BehaviorofrapidlyquenchedV2O5glasatcathodeinlithium.J.Electrochem.Soc.,1989,136(8):213311XueKH,YangH,ZhouYMetal.AstudyoftheZn/V6O13secondarybatery.J.Electrochem.Soc.,1993,140(12):341312WeppnerW,HugginsRA.Determinationofthekineticparametersofmixed-conductingelectrodesandapplicationtothesystemLi3Sb.J.Electrochem.Soc.,1977,124(10),156913MurphyDW,ChristianPA,DisalvoFJetal.Lithiumincorporationbyvanadiumpentoxide.InorganicChemistry,1979,18(10):280014KumagaiN,TannoK.StructuralchangesofNb2O5andV2O5asrechargeablecathodesforlithiumbatery.Electrochimica.Acta,1983,28(1):1715HubS,TranchantA,MesinaR.X-RayinvestigationsonelectroformedLiXV2O5bronzes.Electrochimica.Acta,1988,33(7):99716ProuzetE,MoulinCCD,VilainFetal.Electrochemicalintercalationoflithiumintovanadiumpentaoxide:AninsituX-Rayabsorptionstudy.J.Chem.Soc.,FaradayTrans.,1996,92(1):10317林枫凉,薛立新,朱斌等.锌钒酸酐固态蓄电池.中国科学技术大学学报,1990,20(2):159

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.