Synthesis of Li_(1+x)Mn_2O_4 cathode material for lithium-ion batteries with solution method

Authors

Pei song LIU
Sing quarn LIU
qing Li
Zhao yong CHEN
Bai lan ZHANG
Zuo long YU

Corresponding Author

Zuo long YU

Abstract

The cathode materials Li 1+x Mn 2O 4 were prepared with citric acid complexing and solution impregnating methods.Structure characterization and specific surface area test were performed by means of XRD,BET methods ,the influences of calcination temperature,Li/Mn molar ratio and raw materials on the structure and electrochemical capacity of samples have beem examined.The results showed that the Li/Mn molar ratio and calcimation temperature were the key factors affecting the electrochemical capacity of cathode materias.The optimum conditions for synthesis of Li 1+x Mn 2O 4 cathode material were 0≤x≤0.05 and calcined at 750°C.The initial capacity of the sample reached 120 mAh/g and capacity retention after 50 cycles was 115 mAh/g.

Keywords

Li ion Battery, Spinel structure, Lithium manganese oxide, Complex method, Impergnation method

DOI Link

https://doi.org/10.61558/2993-074X.3228

Publication Date

2000-08-28

Online Available Date

2000-08-28

Revised Date

2000-08-28

Received Date

2000-08-28

Recommended Citation

Pei song LIU, Sing quarn LIU, qing Li, Zhao yong CHEN, Bai lan ZHANG, Zuo long YU. Synthesis of Li_(1+x)Mn_2O_4 cathode material for lithium-ion batteries with solution method[J]. Journal of Electrochemistry, 2000 , 6(3): Article 19.
DOI: 10.61558/2993-074X.3228
Available at: https://jelectrochem.xmu.edu.cn/journal/vol6/iss3/19

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