Cathodic Indirect Oxidation of Organic Compounds(Ⅱ)——Cathodic Indirect Epoxidation of Olefine

Authors

Xue ying ZHANG, Fujian Inst. of Res. on the Structure of Matter, Chinese Acad. of Sci., Xiamen 361012, China; State Key Lab. for Phys. Chem.. of Solid Surfaces, Xiamen ;
Bao qiu CUI, Dept. of Chemistry, Hebei Normal University, Shijiazhuang 050016, China,;
Deng ping GU, Dept. of Chemistry, Hebei Normal University, Shijiazhuang 050016, China,;
Wei LI, Dept. of Electronic Chemistry, Tokyo Institute of Technology, Yokohama 226 8502, Japan;

Corresponding Author

Deng ping GU

Abstract

We described a novel cathodic indirect epoxidation system in which O 2 was first cathodically reduced to H 2O 2. Then VO(acac) 2 was oxidized by H 2O 2 homogeneously to VO(acac) 2OOH which was used to epoxidize some olefine such as maleic, fumaric and crotonic acids. Many affecting factors on the current efficiency were optimized. The research will contribute to the developments of organic electrosynthesis.

Keywords

Cathodic indirect epoxidation, Olefins

DOI Link

https://doi.org/10.61558/2993-074X.1393

Publication Date

2000-08-28

Online Available Date

2000-08-28

Revised Date

2000-08-28

Received Date

2000-08-28

Recommended Citation

Xue ying ZHANG, Bao qiu CUI, Deng ping GU, Wei LI. Cathodic Indirect Oxidation of Organic Compounds(Ⅱ)——Cathodic Indirect Epoxidation of Olefine[J]. Journal of Electrochemistry, 2000 , 6(3): 324-328.
DOI: 10.61558/2993-074X.1393
Available at: https://jelectrochem.xmu.edu.cn/journal/vol6/iss3/8

References

[1 ]　GuDeng ping ,WangRui zhi,ZhangXue ying .Cathodicindirectoxidationoforganiccompounds(Ⅰ )———electrosynthesisofDMSO2 [J].Electrochemistry (inChinese) ,inpress .

[2 ]　ZhangHong kun ,GuDeng ping .Thetechniquesofthepairedelectrosynthesis[J].Electrochemistry (inChi nese) ,1 999,5 (3) :30 4～ 390 .

[3]　TalsiEP ,ChinakovVD ,BabenkeVP ,etal.Roleofvanadiumalkylperoxocomplexesinepoxidationofcy clohexeneandoxidationofcyclohexanebyorganichydroperoxidesinthepresenceofbis(acetylacetonato)vanadyl[J].J .Mol.Catal.,1 993,81 :2 35～ 2 5 4.

[4 ]　MihelichED .Vanadium Catatyzedepoxidations .Ⅰ .anewselectivitypatternforacyclicalcohols[J].Tera hedronLett.,1 979,49:472 9～ 4732 .

[5 ]　ShengMN ,ZajacekJG .Hydroperoxideoxidationscatalyzedbymetals .Ⅲ .epoxidationofdienesandolefinswithfunctionalgroups[J].J .Org .Chem .,1 970 ,35 (6 ) :1 839～ 1 843.

[6 ]　KitamuraM ,YamashitaK ,ImaiH .Studiesonelectrodeprocessesofoxovanadium (Ⅳ ) .Ⅲ .solventeffectonreductionpotetialofvanadylacetylacetonate[J].Chem .Lett .,1 975 ,1 0 71～ 1 0 74.

[7]　Kamaluddin ,SinghHV .Resin supportedvanadium (Ⅳ ) catalysedepoxidationofmaleic ,fumaricandcro tonicacidswithhydrogenperoxide[J].J .Catal.,1 992 ,1 37:5 1 0～ 5 1 2 .

[8]　FuriaFD ,ModenaRecl.G .Metalcatalysisinoxidationbyperoxidespart .5 .onthemechanismofvanadium(Ⅴ )catalysedoxidationbyhydrogenperoxide[J].Trav .Chim .Paysbas ,1 979,98:1 81～ 1 87.

[9]　LiWei,TsutomaNonaka .Developmentofcathodicoxiditionsystemanditsapplicationtopairedelectrosyn thesisofsulfonesandnitrones[J].J .Electrochem .Soc .,1 999,1 46 (2 ) ,5 92～ 5 97.