Cathodic Indirect Oxidation of Organic Compounds(Ⅱ)——Cathodic Indirect Epoxidation of Olefine

Authors

Xue-ying ZHANG, Dept. of Chemistry, Hebei Normal University, Shijiazhuang 050016, China
Bao-qiu CUI, Dept. of Chemistry, Hebei Normal University, Shijiazhuang 050016, China
Deng-ping GU, Dept. of Chemistry, Hebei Normal University, Shijiazhuang 050016, China
Wei LI, Dept. of Electronic Chemistry, Tokyo Institute of Technology, Yokohama 226-8502, Japan

Corresponding Author

Deng-ping GU

Abstract

We described a novel cathodic indirect epoxidation system in which O₂ was first cathodically reduced to H₂O₂. Then VO(acac)₂ was oxidized by H₂O₂ homogeneously to VO(acac)₂OOH which was used to epoxidize some olefine such as maleic, fumaric and crotonic acids. Many affecting factors on the current efficiency were optimized. The research will contribute to the developments of organic electrosynthesis.

Keywords

Cathodic indirect epoxidation, Olefins

DOI Link

https://doi.org/10.61558/2993-074X.1393

Publication Date

2000-08-28

Online Available Date

2000-08-28

Revised Date

2000-03-25

Received Date

1999-11-15

Recommended Citation

Xue-ying ZHANG, Bao-qiu CUI, Deng-ping GU, Wei LI. Cathodic Indirect Oxidation of Organic Compounds(Ⅱ)——Cathodic Indirect Epoxidation of Olefine[J]. Journal of Electrochemistry, 2000 , 6(3): 324-328.
DOI: 10.61558/2993-074X.1393
Available at: https://jelectrochem.xmu.edu.cn/journal/vol6/iss3/8