Abstract
There exists a transition current density of Zn when the normal co_deposition of Zn_Ni alloys at chloride baths turns to anomalous type.The value increases with Cl - concentration, but is independent of pH, this is because the existence of Cl - decreases the evolution overpotential of Ni metal and has a catalytic effect on it.
Keywords
Zn_Ni alloys, Transition current density, Anomalous co_deposition, Catalytic effect
Publication Date
2002-05-28
Online Available Date
2002-05-28
Revised Date
2002-05-28
Received Date
2002-05-28
Recommended Citation
Ren-he YIN, Zheng-hua FANG, Wei-min CAO.
Effect of Cl - on the Transition Current Density of Zn during the Electrodeposition of Zn-Ni Alloys[J]. Journal of Electrochemistry,
2002
,
8(2): Article 19.
DOI: 10.61558/2993-074X.3293
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol8/iss2/19
References
[1] TuZhenmi.Thepresentsituationanddevelopmentofelectrodepostitiongzincandzincbasealloys[J].Plating&Finishing;1994,16(3):3.(inChinese).
[2] LiHuawei.LiuYiuli.CheChenhuan.Currentstatusofsystemzincalloysplating[J].Electroplating&Protec tionControl,1998,101:16.(inChinese).
[3] AtsuyoshiShibuya,TatsuoK ,KimitakeK ,KohjiN .Corrosionsurfacetreatment[J].J .Iron.Steel.Inst.Japan,1980,66:771.
[4] YojiImai.TsuyukiWatanabe.MitsuoKurachi.ElectrodepositionofNi_Znalloysandtheirthermodynamice valuation[J].ElectrochemJapan,1978,46:202.
[5] FuKushimaH ,AklyamaTLee,JYamaguchiM ,HigashiK .MechanismoftheelectrodepositionofzincwithIron_groupmetalsfromsulfatebaths[J].Trans.Japan.Inst.Metals.,1983,24:125
[6] MitsuhiroYasuda,IzumiOhno,ShiroH .Roleofchlorideiononnickelplating[J].J .Surf.Finish.Soc.Japan,1990,41:312
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