Abstract
The following recent studies on the atomic and molecular-perspectives atelectrochemical interfaces using Raman,IR,STM and quantum chemical methed by electrOchemistrygroup in Xiamen University are briefly reviewed. 1.Orientation,charge transfer and bonding of adsorbed molecules. 2.Adsorption effect,electrode potential effect and adatom effect on the electron populations and strength of intramolec ular bonds of the adsorbed molecules. 3.Detailed classification into various types(e. g.,competitive,chemically inductive, physical inductive etc.)of coadsorption on electrodes according to the above-mentioned effects. 4. Single crystal face structure effect and adatom effect on the kinetics and the mechanisms of electrocatalytic oxidation processes of small organic molecules. 5.Electrochemical scanning tunneling microscopy(ECSTM)specially designed for reducing the interference of Faraday current of tip on tunneling current and observations at atomic-molecular level for Cu/HOPG and self-assembled LB film.
Publication Date
1995-02-28
Online Available Date
1995-02-28
Revised Date
1995-02-28
Received Date
1995-02-28
Recommended Citation
Zhaowu Tian.
Atomic and Molecular-Perspectives in Electrochemical Interfaces[J]. Journal of Electrochemistry,
1995
,
1(1): 1-7.
DOI: 10.61558/2993-074X.1256
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol1/iss1/1
References
1. 田中群,孙世刚,罗瑾杨勇.现场光谱电化学研究新进展.物理化学学报,1994,10(9):860
2. 田中群,李五湖,穆纪千,毛秉伟,陈捷光,卓向东,郑伟,王锋,颜恩柔.Raman-STM联用系统及初步实验.物理化学学报,1994,10(12):1062
3. LiWH,TianZQ,GaoJS,XueQ.In-situ Time resolved Raman Spectroscopic Studies of Silver Electrede in NaSCN Solution.Chinese Chemical Letter,1993,4:829
4. TianZQ,LinWF,MaoBW.Potential Averaged Surface-Enhanced Raman Spectroscopic SCN--Adsorbedat Ag Electrodes.J.Electroanal.Chem.,1991,319:403
5. 田中群,李五湖,毛秉伟,钟起玲.电位平均SERS技术研究物种在整个吸附电位区间的行为.科学通报,1993,15:1439
6. 查英华,魏宝明,田中群,林昌健.表面增强拉曼光谱用于不锈钢缓蚀机理的研究,腐蚀科学与防护技术.1994,6:58
7. Sun SG,Chen AC,Huang TS,Li JB,Tian ZW,Electrocatalytic Properties of Pt(111),Pt(332),Pt(331),andPt(110)single crystal Electredes towards Ethylene Glyco I Oxidation in Sulphuric Acid Solutions.J.ElectroanalChem.,1992,340:213
8. 孙世刚,ClavilierJ.铂单晶(210),(310)和(610)阶梯晶面在甲酸氧化中的电催化特性.高等学校化学学报,1990,11:998
9. 孙世刚,陈爱成,黄探,李竟白.一种金属单晶电极制备方法的建立和Cu ̄(2+)在铂单晶上UPD过程的研究.高等学校化学学报,1992,13:390
10. 孙世刚.吸附原子电催化机理的研究铂单晶(100)晶面上Pb、Cd吸附原子在甲酸电氧化中的助催化特性.物理化学学报,1990,3:364
11. Lin WF,Sun SG,Tian ZQ,Tian ZW. A Microscopic Modelling and Quantum Chemical Treatment of Adsorption at Electrochemical Interfaees.ChineseScinenceBulletin,1994,39:27
12. Lin WF,Tian ZQ,Sun SG,Tian ZW. Quantum Chemistry Studieds on Electronic Propor times of CN- Adsorbed on Silver Electrodes.ElectrochimicaActa,1992,37(2):211
13. 林文锋.电化学吸附及电催化过程的量子化学和现场光谱的联合研究,厦门大学博士学位论文,1991
14. Lin WF,Sun SG,Tian ZQ,Tian ZW.Quantum Chemistry and in situ FTIR Spectroscopy Studies on Potential-dependent Properties of CO Adsorbed on Pt Electredes.ElectrochemicaActa,1993,38:1107
15. Tian ZQ,Lin TQ,Lian YZ.Surface-Enhanced Raman Scattering of Water in Highly Concentrated NaClO4 Systems.ScienceinChina(SeriesB),1990,9:1025
16. Tian ZQ,Lin TQ,Lian YZ.SERS Studies on Interfacial Water in Concentrated NaClO4 Solutions.J.Electroanal.Chem.,1989,265:277
17. Tian ZQ,Sigalaev SK,Zou SZ,Mao BW.The Observation of SERS of Water in a Wide Potential Range.Electrochim.Acta,1994,39,2195
18. Tian ZQ,Mao BW.SERS Characterization of Adsorbed Waterat Very Negative Potentials. Chinese Chemical Letter,1993,4:625
19. 邹受忠,张韫鸿,陈燕霞,田中群.水在Ag电极上取向与结构的SERS研究.高等学校化学学报,1995,16(2)
20. LiWH,MaoBW,TianZQ.Surface-Enhanced Raman Spectroscopic Studies on Silver Electrodes in the Presence of 2-Mercaptopyrimidine.Journal of Raman Spectroscopy,1995,26:56
21. 田中群,李五湖,陈衍珍.电位平均SERs技研究二巯基嘧啶与银电极的作用.光散射学报,1992,4:121
22. 田中群,雷良才,景遐斌.苯胺在银和金电极上的表面增强拉曼光谱.物理化学学报,1988,4:458
23. 林仲华,王逢春,田中群.2-氨基咪啶对铜的缓蚀机理.物理化学学报,1992,8:87
24. 田中群.表面增强拉曼光谱研究电化学中的共吸附现象.物理化学学报,1988,4:344
25. 李五湖.表面增强拉曼光谱技术研究电化学吸附及其与扫描隧道显微镜联用系统的建立.厦门大学博士学位论文,1994
26. Tian ZQ,Li WH,Mao BW,Gao JS.Surface Enhanced Raman Spectrcocopic Studies on Structural Dynamics of Coadsorption of Thiourea and at Ag Electredes.J.Electroanal.Chem.,1994,379:271
27. Tian ZQ,Fleischmann M. Raman Spectroscopic Studies on the Complexation and Adsorbed Behaviour of Thiourea.Chem.J,ChineseUniv.,1989,5:265
28. Tian ZQ,Lian YZ.Fleischmann M. In situ Raman Spectroscopic Studies on Coadsorption of Thiourea with Anions at Ag Electredes.ElectrochimicaActa.,1990,35:879
29. 田中群,李五湖,高劲松,毛秉伟.SERS谱峰对电极电位阶跃的不同响应速率的证据.物理化学学报,1993,9(6):721
30. Lin WF,Sun SG,Tian ZW. Investigations of Coadsorption of Carbon Monoxide with SorBi Adatoms at a PlatinumElectredebyin-situFTIRSpectrosocopyandQuantumChemistryAnalysis.J.Electroanal.Chem.,1994,364:1
31. Suarez P,P.Suarez,Wu HH,Sun SG.Mechanism of Glucose Electro-Oxidation:Voltammetric and Insitu FTIR Reflectance Spoctroscopic Studies.ChineseScienceBulletin,1992,37:997
32. Sun SG,Yang DF,Tian ZW.In situ FTIR Studies on the Adsorption and Oxidation of n-Propanol and Isopropanol at a Platinum Electrode In Sulphuric Acid Sollutions.J.Electroanal.Chem.,1990,289:177
33. Sun SG,Yang DF,Tian ZW,In situ FTIR Spoctroscopic Studies of Electrocatalytic Processes----Oxldation of n-Propanol on Pt Electrede.ProgressinNaturalScience,1991,1:48
34. SunSG,ChenAC, In Situ FTIR Features During Oxygen A dsorption and Carbon Monoxide at a Platinum Electrode In Dilute Alakaline Solutions.J.ElectroanalChem.,1992,323:319
35. Sun SG,Lin Y.Current Oscillation During Oxidation of Formic Acid on Pt/S band Electrode.Progress in Natural Science,1992,2:351
36. SunSG.³KineticsAspectsofOxidationofIsopropanolonPtElectrodeInvestigatedbyinsituTime-resolvedFTIRSpectroscopy³.J.Electroanal.Chem.,1994,375:40137SunSG.³KineticsofDissociativeAdsorptionofFormicacidonPt(100),Pt(610),R(210),Pt(110)SingleCrvstalEIectrodeinPerchloricAcidSolutions³.J.Electroanal.Chem.,1994,370:273
38. 孙世刚,杨东方,田昭武.丙三醇在Pt电极上吸附和氧化过程的原位FTIR反射光谱研究.化学学报,1992,50:533
39. 孙世刚,王津建,穆纪千.甲酸在Pt(100)单晶电极表面解离吸附过程的动力学.物理化学学报,1992,8:732
40. 陈爱成,孙世刚.乙二醇在铂电极上吸附和氧化过程的现场FTIR光谱研究,高等学校化学学报,1994,15:401
41. 孙世刚,扬东方,田昭武.酸性介质小1,2-丙二醇在铂电极上吸附和氧化过程的原位FTIR反射光泽研究.物理化学学报,1992,8:59
42. 陈声培,孙世刚,黄泰山.玻碳表面铂黑电极的结构与电催比活性.科学通报,1994,39:2046
43. Tian ZW,Zhuo XD,Mu JQ,Ye JH,Fen ZD,Mao HW,Bai CL,Dai CD.A New Electrochemical Scanning Tunneling Microscope.Ultramicroscopy,1992,42:460
44.Mao BW,Ye JH,Zhuo XD,Mu JQ,Fen ZD,Tian ZW.A New Method of STM Tip Fabrication for In-Situ Electrochemical Studies.Ultramicroscopy,1992,42:464
45. 李春增,谢兆雄,毛秉伟,卓向东,穆纪千,叶建辉,冯祖德,田昭武.CU在HOPG上电化学沉积的原子分辩ECSTM现场观测.高等学校化学学报,1993,14:706
46. 李春增.电化学扫描隧道显微技术,厦门大学博士学位论文,1993
47. ZhangYH,XieZX,HuaBZ,MaoBW,ChenYZ,TianZW.STM Observations of a Self-Assebled structure of Stearic Acid Langmuir-Blodgett Films with Molecular Resolution.To be published
48. Tian ZW,Fen ZD,Tian ZQ,Zhuo XD,Mu JQ,Li CZ,Lin HS,Ren B,Zhuo ZX,Hu WL.Confined Etchant Layer Technique for Two-Dimensional Lithography at High Resolution using Electrochemical Scanning Tunnelling Microscopy.FaradayDiscussion,1992,94:37
49. TianZW,LinZH,TianZQ,LuoJ,LinHS,HuWL.Confined Etchantlayer Technique for Photo Electrochemical Nanolithography.in ³photochemical and Photoelectrochemical Conversion and Storage of SolarEnergy³.International Academic Publisher Beijing,1992:249
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