Abstract
The titanium substrates were bombarded with 1×10 ̄(17)~5×10 ̄(17)ions·cm ̄(-2) ofpalladium at the room temperature. The surface composition of implanted electrede and concentration-depth profiles of various elements were measured by AES. The electrored uction processes ofnitrobenzene(NB)in 0.1 mol/L NaOH solution at Pd/Ti electrodes have been investigated by cyclicvoltaivimetry.The results show that the palladium implanted titanium electrodes exhibit a high catalyticactivity in the electroreduction of NB. The NB radical anion,which is the product of one-electronelectroreduction of NB,was detected by ESR in-situ in conjunction with electrochemical methods. Aniline was also detected as a product of electroreduction of NB by using UV-spectra in-situ. According to the experimental results,the electroreduction mechanisms of NB are discussed.
Keywords
Ion implantation, Electroreduction, Nitrobenzene, Titanium electrode, Palladium
Publication Date
1995-02-28
Online Available Date
1995-02-28
Revised Date
1995-02-28
Received Date
1995-02-28
Recommended Citation
Zhongda Wu, Xianjun Zhu, Hongsen Wang.
Electroreduction of the Nittobenzene on Titanium Electrode Implanted with Palladium[J]. Journal of Electrochemistry,
1995
,
1(1): 38-43.
DOI: 10.61558/2993-074X.1261
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol1/iss1/6
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