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Abstract

The redox properties of Ln(MW_(11))_2(M=As, Ti, Ga; Ln=La,ce,pr,Nd,Sm,Eu,Gd , Dy ) are systematically studied.It has been found that the redox order is La(AsW_(11))_2>La(TiW_(11))_2>La(GaW_(11))_2.The reduction process of Ln(MW_(11))_2 anion has been discussed.

Keywords

Undecatungstometalate lanthanetes, Redox, Keggin structure

Publication Date

1995-11-28

Online Available Date

1995-11-28

Revised Date

1995-11-28

Received Date

1995-11-28

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