Abstract
The ferrate(Ⅵ) was synthesized by electrochemical anodic oxidation. The effects of preparation conditions on the current yield of ferrate(VI) synthesis have been studied in this work. The experimental results showed that grey cast iron as an anodic material is suitable for electrochemical synthesis and NaOH solution as an electrolyte results in a higher current yield than KOH solution. The highest current yield was obtained at a current density (4.54) mA· cm~(-2),temperature 20 ℃ and 14 mol·dm~(-3) NaOH. In this case, a current yield of 68.5% was obtained by electrolysis for 1 h.
Keywords
Ferrate(VI), Current yield, Polarization curve
Publication Date
2004-02-28
Online Available Date
2004-02-28
Revised Date
2004-02-28
Received Date
2004-02-28
Recommended Citation
Jia-ju XU, Jian-ming WANG, Wei-hua YANG, Cheng CHEN, Jian-qing ZHANG.
Electrochemical Synthesis of Ferrate(VI) by Anodic Oxidation[J]. Journal of Electrochemistry,
2004
,
10(1): 87-93.
DOI: 10.61558/2993-074X.1551
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol10/iss1/15
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