•  
  •  
 

Corresponding Author

Bao-lian YI(blyi@dicp.ac.cn)

Abstract

In this paper, sPTFS/PTFE composite membranes for PEMFC were obtained by impregnating two kinds of sulfonated poly-α,β,β- trifluorostyrene resin with different EWs into the porous PTFE substrate membranes. Water uptake, proton conductivity, mechanical strength and fuel cell performance of these two composite membranes were measured. Water uptake and proton conductivity were greatly reduced and mechanical strength was increased by composition in comparison with homogeneous membranes. Under the operating condition: T_(Cell)=80 ℃, P_(H_2)=0.2 MPa,P_(O_2)=0.2 MPa, fuel cell performance of the two composite membranes were better than that of Nafion~115. The fuel cell performance of composite membrane with low EW was better than that with high EW, but the stability of former is worse than that of latter.

Keywords

Poly -α, β, β- trifluorostyrene, Composite membrane, Proton Exchange Membrane Fuel Cell(PEMFC), Cell performance

Publication Date

2004-02-28

Online Available Date

2004-02-28

Revised Date

2004-02-28

Received Date

2004-02-28

References

[1] BrianCH.Steele&angelicaheinzel,materialsforfuel_celltechnologies[J].Nature,2001,414:345.
[2] SavadogoO.Emergingmembranesforelectrochemicalsystems:(1)Solidpolymerelectrolytemembranesforfuelcellsystems[J].JournalofNewMaterialsforElectrochemicalSystems,1998.
[3] AlfredESteck.CharlesStoneSubstituedα,β,β_trifluorostyrenebasedcompositemembranes[P].U.S.Patent5834523.
[4] JinzhuWei,CharlesStone,AlfredESteck.Trifluorostyreneandsubstitutedtrifluorostyrenecopolymericcompositionsandion_exchangemembranesformedtherefrom[P].U.S.Patent5422411.

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.